A 46.2 L sample of gas exerts 237.4 mm Hg pressure at 139.2 ºC. What volume does the gas have at 702.4 mm Hg and 63.4 ºC?
A. 12.7
B. 2.40
C. 7.11
D. 112

Answers

Answer 1

7.111 L is the volume of gas with 702.4 mm Hg and 63.4 ºC.

What is an ideal gas equation?

The ideal gas law (PV = nRT) relates the macroscopic properties of ideal gases. An ideal gas is a gas in which the particles (a) do not attract or repel one another and (b) take up no space (have no volume).

Given data:

\(V_1=46.2 L\)

\(P_1=237.4 mm Hg\)

\(T_1=139.2 ºC\)

\(V_2=?\)

\(P_2=702.4 mm Hg\)

\(T_2=63.4 ºC\)

Using the given below formula:

\(\frac{V_1 X P_1}{T_1} = \frac{V_1 X P_1}{T_2}\)

\(\frac{46.2 L X 237.4 \;mm Hg}{139.2} = \frac{V_2 X 702.4 mm Hg}{63.4 ºC}\)

\(V_2\) = 7.111 L

Hence, 7.111 L is the volume of gas with 702.4 mm Hg and 63.4 ºC.

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Related Questions

should i get this? i heard it smells good

should i get this? i heard it smells good

Answers

Answer: Maybe not? Unless you care about namebrand, theres lots of dupes.

The substances produced in a chemical reaction are called?

Answers

Answer:

Products

Explanation:

The end results of a chemical reaction are called products

-> In chemistry, a product is a substance that is formed as the result of a chemical reaction.

-> Not many other ways to word this as it is a definition

Have a nice day!

     I hope this is what you are looking for, but if not - comment! I will edit and update my answer accordingly. (ノ^∇^)

- Heather

Answer:

Products

General Formulas and Concepts:

Reactions

Reactants and Products in RxNs

Explanation:

The substances used in a chemical reaction is called the reactants, usually located on the left side of the arrow (if pointing right).

The substances produced in a chemical reaction is called the products, usually located on the right side of the arrow (if pointing right).

RxN examples:

Reactant + Reactant → Product + Product

Reactant + Reactant → Product

Reactant → Product + Product

Topic: Honors Chemistry

A student noticed that the size of the hot pack becomes bigger when magnesium sulfate reacts with water. She thinks that more atoms are produced that make the hot pack grow bigger. Do you agree?

Answers

Answer:

No

Explanation:

In the hot pack, as the water reacts with the magnesium sulfate, the pack becomes bigger is not an indication that new atoms have been created or produced.

As with all chemical reactions, they all obey the law of conservation of matter which states that "in chemical reactions, matter is neither created nor destroyed but atoms simply recombine".

The reason why the hotpack becomes bigger is because the atoms gain more volume.

Select the most ideal gas situation:

Hydrogen and steam.

Answers

When hydrogen and steam are both present in a gas at the same pressure and temperature, this is the ideal gas condition. This is so because according to the ideal gas law, an ideal gas's pressure, volume, and temperature are all precisely proportional to one another.

This indicates that when the two gases have the same temperature and pressure, the two gases will also have the same volume. As a result, the gases are in their ideal state, having the same volume and pressure but retaining their distinct chemical compositions.

This is perfect because it enables the two gases to interact with one another in a predictable way, allowing for the measurement and prediction of the gases' behaviour.

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Classify each property according to whether it is displayed by metals or by nonmetals
a. low melting point b. shiny dull c. poor conductor d. ductile e. malleable f. brittle g. good conductor h. high melting point

Answers

a. low melting point: Nonmetals. b. shiny: Metals. c. poor conductor: Nonmetals. d. ductile: Metals. e. malleable: Metals. f. brittle: Nonmetals. g. good conductor: Metals. h. high melting point: Metals

a. Low melting point is generally displayed by nonmetals. Metals tend to have high melting points.

b. Metals are typically shiny due to their ability to reflect light.

c. Nonmetals are generally poor conductors of heat and electricity.

d. Metals are ductile, meaning they can be drawn into thin wires without breaking.

e. Metals are malleable, meaning they can be hammered into thin sheets or shapes without shattering.

f. Nonmetals are usually brittle, meaning they are prone to breaking or shattering when subjected to stress.

g. Metals are good conductors of heat and electricity.

h. Metals typically have high melting points compared to nonmetals.

It's important to note that these are general trends and not absolute characteristics for all metals or nonmetals. Some exceptions or variations may exist within specific elements or compounds.

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When 21.5 g of CH4 gas reacts with 387.5 g O2 gas, how much CO2 is formed?

Answers

Answer:

Mass = 58.96 g

Explanation:

Given data:

Mass of CH₄ = 21.5 g

Mass of O₂ = 387.5 g

Mass of CO₂ formed = ?

Solution:

Chemical equation:

CH₄ + 2O₂       →   CO₂ +  2H₂O

Number of moles of CH₄:

Number of moles = mass / molar mass

Number of moles = 21.5 g/ 16 g/mol

Number of moles = 1.34 mol

Number of moles of O₂ :

Number of moles = mass / molar mass

Number of moles = 387.5 g/ 32 g/mol

Number of moles = 12.1 mol

now we will compare the moles of CO₂  with O₂  and CH₄.

                       O₂             :          CO₂

                          2             :            1

                          12.1          :          1/2×12.1 = 6.05 mol

                        CH₄          :          CO₂

                           1              :            1

                          1.34           :         1.34

Number of moles of CO₂ produced by  CH₄ are less thus it will limiting reactant.

Mass of  CO₂:

Mass = number of moles × molar mass

Mass =  1.34 mol × 44 g/mol

Mass = 58.96 g

Is it technically correct to call ionic compounds molecules?

Answers

Answer:

uh yeah I think so technically

Answer:

no

Explanation:

8. Standard reduction potentials are given for reduction half-reactions relative to the hydrogen half-reaction. In Part 1 of this experiment, you will determine reduction potentials rela- tive to the reduction of copper and silver. Predict what the reduction potentials should be relative to the silver and copper electrodes. It may help to think of this as a vertical ruler. As you move the ruler up, the zero shifts up and the numbers change accordingly. E (volts) STANDARD REDUCTION POTENTIALS AT 25°C E (volts) E (volts) Referenced to Referenced to the Hydrogen the Copper Electrode Electrode Half-Reaction Referenced to the Silver Electrode 0.80 0.80 0.0 Ag+ + e + Ag (5) Cu2+ + 2e → Cu () 0.34 0.0 0,34 2H+ + 2e → H2(g) 0.0 Not measured Not measured Fe2+ + 2 e Fe (s) - 0.41 Zn2+ + 2e → Zn (5) - 0.76

Answers

The reduction potential of Cu²⁺ is 0.34 volts and the reduction potential of Ag⁺ is 0.8 volts

The reduction potentials of Ag⁺ and Cu²⁺ relative to the silver and copper electrodes, respectively, can be found by using a vertical ruler to shift the zero point of the reference hydrogen half-reaction.

Relative to the silver electrode, the reduction potential of Ag⁺  is 0.8 volts and

The reduction potential of Cu²⁺ is 0.0 volts.

Relative to the copper electrode, the reduction potential of Ag⁺  is 0.0 volts and

The reduction potential of Cu²⁺ is 0.34 volts.

The reduction potentials of the other half-reactions (Fe²⁺, Zn²⁺) cannot be measured relative to the silver and copper electrodes, as they are not included in the vertical ruler.

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Quantum Theory proposes electrons may
be found in orbitals, which are based on
what?
Bohr's planetary model
Thompson's Plum Pudding Model
the probability of finding an electron in an
area around the nucleus
The Heisenberg-Rutherford Model

Answers

         A quantum is the smallest discrete unit of a phenomenon (plural: quanta). For instance, a photon is a quantum of light, while an electron is a quantum of electricity. Quantum is a Latin word that means "quantity" or "how much?" Anything that can be measured is something that can be quantified.

How does quantum theory connect to Bohr's model?

             Bohr's hypothesis, often known as quantum theory, postulated that electrons move around the nucleus according to the classical principles, but with restrictions on the orbits they can take and the energy they lose as radiation when they change orbits.

        The Bohr model, also known as the Rutherford-Bohr model, was first proposed by Niels Bohr and Ernest Rutherford in 1913 and describes an atomic system with an orbiting system of electrons and a small, dense nucleus that is similar to the Solar System in structure but is attracted by electrostatic forces rather than gravity.

           A small positively charged nucleus is encircled by rotating negatively charged electrons in set orbits, according to the Bohr Atomic Model. He came to the conclusion that an electron will have more energy if it is placed far from the nucleus and less energy if it is located close to the nucleus.

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Quantum Theory proposes electrons maybe found in orbitals, which are based onwhat?Bohr's planetary modelThompson's

if you start with 10.00 grams of a radioactive isotope, and 5.00 grams remain after 10 days, then we would say the half-life is what?

Answers

The calculated half-life of -10 does not make sense as a positive value is expected.

To determine the half-life of a radioactive isotope, we can use the formula for exponential decay:

N(t) = N₀ * (1/2)^(t / t₁/₂)

where:

N(t) is the amount of the isotope remaining at time t

N₀ is the initial amount of the isotope

t is the elapsed time

t₁/₂ is the half-life of the isotope

In this case, we know that the initial amount N₀ is 10.00 grams, and the amount remaining after 10 days N(t) is 5.00 grams. Plugging in these values, we can solve for the half-life (t₁/₂).

5.00 = 10.00 * (1/2)^(10 / t₁/₂)

Dividing both sides by 10.00:

0.5 = (1/2)^(10 / t₁/₂)

Taking the logarithm (base 1/2) of both sides:

log₁/₂(0.5) = 10 / t₁/₂

Simplifying:

-1 = 10 / t₁/₂

Rearranging the equation:

t₁/₂ = 10 / (-1)

t₁/₂ = -10

The half-life obtained from this calculation is -10, which doesn't make sense as a time measurement. It's important to note that the half-life is a positive value representing the time it takes for half of the radioactive substance to decay.

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how do you know when a chemical change has occurred?

Answers

Answer:

The five conditions of chemical change: color change, formation of a precipitate, formation of a gas, odor change, temperature change

Hope that helps

PLEASE HELP!!! Explain how the periodic table tells you about the atomic structure of an element. (this is for my physical science class)

Answers

Answer:

The number of outer shell electrons determines the group number of the element. The number of occupied principle quantum shells (energy levels) determines the period of the element. The proton number determines the element itself and its position.

Explanation:

PLEASE HELP:
Which of the following would go in the center circle if you were making a web outline about pollution?
Carbon emissions
Causes of pollution
Nuclear waste
Oil spills

Answers

Answer:

Oil spills

Explanation:

I've done it before

Electronic configuration of 11N

Answers

Answer:

The Electronic configuration of 11N is

[Ne]3s1

Calculate the standard potential for the following galvanic cell:

Ni(s) | Ni2+(aq) | Ag+(aq) | Ag(s)

which has the overall balanced equation:

Ni(s)+2Ag+(aq)→Ni2+(aq)+2Ag(s)

Express your answer to three significant figures and include the appropriate units.

Reduction half-reaction E∘ (V)

Ag+(aq)+e−→Ag(s) 0. 80

Cu2+(aq)+2e−→Cu(s) 0. 34

Ni2+(aq)+2e−→Ni(s) −0. 26

Fe2+(aq)+2e−→Fe(s) −0. 45

Zn2+(aq)+2e−→Zn(s) −0. 76

Answers

The standard potential for the given galvanic cell is +1.06 V.

To calculate the standard potential for the given galvanic cell, we need to determine the individual reduction potentials of the half-reactions and then subtract the potential of the anode (where oxidation occurs) from the potential of the cathode (where reduction occurs).

Given reduction half-reaction potentials:

Ag+(aq) + e^− → Ag(s): E∘ = +0.80 V

Ni2+(aq) + 2e^− → Ni(s): E∘ = -0.26 V

Since we have the reduction potentials for both half-reactions, we can directly calculate the standard potential for the cell:

E∘(cell) = E∘(cathode) - E∘(anode)

= E∘(Ag+(aq) + e^− → Ag(s)) - E∘(Ni2+(aq) + 2e^− → Ni(s))

E∘(cell) = +0.80 V - (-0.26 V)

= +1.06 V

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lone pairs and double bonds are more spread out in space than a bonding pair. the result is that they exert greater repulsion o

Answers

Lone pairs and double bonds in a molecule tend to occupy more space and exert greater repulsion compared to bonding pairs. This is due to the electron density associated with lone pairs and double bonds, which leads to an increased electron-electron repulsion.

In a molecule, bonding pairs are formed by the sharing of electrons between two atoms, and they tend to be located closer to the atomic nuclei. On the other hand, lone pairs and double bonds involve non-bonding electrons that are not involved in the sharing between atoms and occupy more space around the atom. The greater repulsion exerted by lone pairs and double bonds arises from the fact that electrons repel each other due to their negative charges. This repulsion influences the overall molecular geometry and affects the bond angles between atoms. Therefore, the spread-out nature of lone pairs and double bonds in space leads to increased electron-electron repulsion, which can impact the molecular shape and bond angles in a molecule.

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1. Which of the following species determines the chemical properties of an atom?
A. Electron
B. Neutron
C. Nucleus
D. Proton


2. The following glasswares are used to measure the volume of liquids except
A. graduated beaker
B. pipette
C. test tube
D. burette

 
3. Pauli exclusion principle is related to
A. quantity of electrons in the valence shell
B. filling the orbitals with lower energy first
C. the filling of degenerated orbitals
D. quantum numbers of electrons

Answers

Explanation:

The number of electrons, in turn, determines the chemical properties of the atom. Protons contribute to the mass of an atom and provide the positive charge to the nucleus. The number of protons also determines the identity of the element

Answer:

Question 1: (A)

The number of electrons determine the chemical properties of an atom.

Question 2:  (C)

Test tube cannot measure the volume of liquids rather they are used in chemical reactions

Question 3: (D)

Pauli's Exclusion Principle states that no two electrons in the same atom can have identical values for all four of their quantum numbers.

what element present in protein is not present in carbohydrate or fat? a) carbon b) hydrogen c) oxygen d) nitrogen

Answers

Answer:

The element that is present in proteins but not in carbohydrates or fats is d) nitrogen.

Explanation:

Proteins are the only macromolecules among proteins, carbohydrates, and fats that contain nitrogen atoms. Nitrogen is a crucial component of amino acids, the building blocks of proteins, whereas carbohydrates and fats primarily consist of carbon, hydrogen, and oxygen atoms.

How many moles of potassium in 73.56g of potassium chlorate (V) (KClO 3 )?

Answers

Answer:

Approximately \(0.6003\; \rm mol\) formula units.

Explanation:

Formula Mass of KClO₃

Look up the relative atomic mass data for \(\rm K\), \(\rm Cl\), and \(\rm O\) on a modern periodic table:

\(\rm K\): \(39.908\).\(\rm Cl\): \(35.45\).\(\rm O\): \(15.999\).

The relative atomic mass of an element is numerically equal to the mass (in grams) of one mole of its atoms. For example, the relative atomic mass of \(\rm K\) is \(39.908\). Therefore, the mass of one mole of \(\rm K\!\) atoms should be \(39.908\; \rm g\).

Each \(\rm KClO_3\) "formula" unit includes one \(\rm K\) atom, one \(\rm Cl\) atom, and three \(\rm O\) atoms. Therefore, one mole of \(\rm KClO_3\!\) formula units would include:

one mole of \(\rm K\) atoms, one mole of \(\rm Cl\) atoms, and three moles of \(\rm O\) atoms.

From the relative atomic mass of these three elements:

The mass of one mole of \(\rm K\) atoms would be \(39.908\; \rm g\).The mass of one mole of \(\rm Cl\) atoms would be \(35.45\; \rm g\).The mass of three moles of \(\rm O\) atoms would be \(3 \times 15.999\; \rm g = 47.997\; \rm g\).

Combining these three parts should give the mass of one mole of \(\rm KClO_3\) formula units:

\(\begin{aligned}& M(\mathrm{KClO_3}) \\ &= 39.908 + 35.45 + 3 \times 15.999 \\ &= 122.545\; \rm g \cdot mol^{-1}\end{aligned}\).

Number of moles of KClO₃ formula units in the sample

The formula mass of \(\rm KClO_3\) is \(M(\mathrm{KClO_3}) = 122.545\; \rm g \cdot mol^{-1}\), meaning that the mass of one mole of \(\rm KClO_3\!\) formula units would be \(122.545\; \rm g\!\).

The mass of this \(\rm KClO_3\!\!\) sample is \(m(\mathrm{KClO_3}) = 73.56\; \rm g\). The number of moles of formula \(\rm KClO_3\!\) units in this sample would be:

\(\begin{aligned}n(\mathrm{KClO_3}) &= \frac{m(\mathrm{KClO_3})}{M(\mathrm{KClO_3})} \\ &= \frac{73.56\; \rm g}{122.545\; \rm g \cdot mol^{-1}} \approx 0.6003\; \rm mol\end{aligned}\).

73.56 g of potassium chlorate (v), KClO₃ contains 0.6 mole of potassium, K.

To know the exact number of mole of potassium (K) in 73.56 g of potassium chlorate (v), KClO₃ do the following:

Step 1:

Determination of the number of mole in 73.56 g of potassium chlorate (v), KClO₃

Mass of KClO₃ = 73.56 g

Molar mass of KClO₃ = 39 + 35.5 + (16×3)

= 39 + 35.5 + 48

= 122.5 g/mol

Mole of KClO₃ =?

\(Mole =\frac{mass}{molar mass}\\\\Mol KClO_{3} = \frac{73.56}{122.5}\)

Mole of KClO₃ = 0.6 mole

Step 2:

Determination of the number of mole of potassium, K in 0.6 mole (i.e 73.56 g) of KClO₃

Considering the molecular formula of potassium chlorate (v), KClO₃, we can see that:

1 mole of KClO₃ contains 1 mole of K.

Therefore, 0.6 mole of KClO₃ will also contain 0.6 mole of K.

Therefore, we can conclude that 73.56 g of KClO₃ contains 0.6 mole of potassium, K.

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two types of thermometers and their characteristics ​

Answers

Answer:

Touch, or contact, thermometers must touch the body in order to measure temperature. Remote, or no-contact, thermometers can measure body temperature without touching the skin.

Explanation:

hope this helps

What is the volume of 0.200 mol of an ideal gas at 200. kPa and 400. K?
Use P V equals n R T. and R equals 8.314 StartFraction L times kilopascals over moles time K EndFraction..

Answers

3.3256 Liters

See the image I have shared to you above

What is the volume of 0.200 mol of an ideal gas at 200. kPa and 400. K?Use P V equals n R T. and R equals

Answer:

B. 7.2k

Explanation:

took the test ;)

In the early twentieth century , what was alexander fleming's hypothesis concerning the relationship between a yellow green mold and certain strains of bacteria

Answers

Answer:

Explanation:

Alexander Fleming's hypothesis was that the juice that was produced by the mold that appeared in the petri dishes was killing the bacteria growing there (streptococcus, meningococcus and the diphtheria bacillus).

Answer:

 

He thought the mold had released a chemical that prevented the bacteria’s growth.

Explanation:

Gradpoint

What is required to make an object at rest move

Answers

Answer:

Newton's First Law is the law of inertia. An object with no net forces acting on it which is initially at rest will remain at rest. If it is moving, it will continue to move in a straight line with constant velocity. F is the net force acting on an object.

Explanation:

yay hope this helps.

it need force or something

1. A stock solution has a volume of 57.86 mL and a molarity of 3.35M. If 125mL of water is added to the stock solution what is the new molarity?

2. 22.10mL of 1.20M solution has been added to 100 mL of water. What is the final molarity?

3. A stock solution has a volume of 65.69 mL and a molarity of 3.79M. If 75mL of water is added to the stock solution what is the new molarity?

4. 72.86mL of 0.15M solution has been added to 200 mL of water. What is the final molarity?

I need help with these questions, please

Answers

The molarity of the following subquestions are as follows;

The new molarity is 1.06 MThe final molarity is 0.22 MThe new molarity is 1.77 MThe final molarity is 0.0401 M

How to calculate molarity?

The molarity of a solution can be calculated using the following expression;

CaVa = CbVb

Where;

Ca and Va = initial concentration and volumeCb and Vb = final concentration and volume

QUESTION 1:

57.86 × 3.35 = 182.86 × Cb

193.831 = 182.86Cb

Cb = 1.06M

QUESTION 2:

22.10 × 1.2 = 122.10 × Cb

26.52 = 122.10Cb

Cb = 0.22 M

QUESTION 3:

65.69 × 3.79 = 140.69 × Cb

248.9651 = 140.69Cb

Cb = 1.77 M

QUESTION 4:

72.86 × 0.15 = 272.86 × Cb

10.929 = 272.86Cb

Cb = 0.0401 M

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What could you say about the melting point of CO2?

O None of these answers are correct
O I'm not sure CO2 isn't an ionic compound.
O CO2 doesn't melt
O high melting point

Answers

Answer:

None of these answers are correct.

CO2 is a covalent not ionic compound

It DOES melt, though at a very low temperature

Its melting point is negative, not high

Explanation:

the equation for the combustion of methane is

CH4+ 2O2——->CO2+2H2O

if you have 5 moles of oxygen how many moles of CO2 could be produced?

Answers

the moles of CO2(g) =2.5moles

I hope this help

the equation for the combustion of methane is CH4+ 2O2->CO2+2H2Oif you have 5 moles of oxygen how

Ned help with this question​

Ned help with this question

Answers

Answer:
Density = 3

Explanation:
Density = Mass/volume
D = 45/15
D = 3

I hope this helps :)
The density is 3 (or 3.0 counting significant figures) g/cm^3

URGENT!!
which has the largest London dispersion force out of the ones listed

URGENT!!which has the largest London dispersion force out of the ones listed

Answers

The answer to this question is HBr

The visible light is a short segment of the electromagnetic spectrum.

Yes or No​

Answers

Answer:

Yes

Explanation:

The visible light spectrum is the segment of the electromagnetic spectrum that the human eye can view.

A gas has a volume of 150 cm3. Convert this volume into mL

Answers

Answer:

The answer is

150 mL

Explanation:

To convert the volume from cm³ to mL we use the conversion

1 cm³ = 1 mL

So from the question

if 1 cm³ = 1 mL

Then 150 cm³ = 150 mL

Hope this helps you

Other Questions
a customer writes 1 xyz sep 45 put at 6 and 1 xyz sep 35 call at 6 when xyz is at 40. before expiration, if xyz is at 43, and the customer closes her positions at intrinsic value, the customer has A)a $200 loss.B)a $200 gain.C)a $600 gain.D)a $600 loss Complete the solution of the equation. Find thevalue of y when x equals 0.6x - 2y = 14 Nadiya and Jrgen are baking cookies for a party. The cookie recipe calls for 200 grams of flour. Nadiya measures this amount out, with an absolute error of 3 grams. Two people bake in kitchenCalculate the relative error of Nadiya's flour measurement. Enter your answer as a decimal or percentage and round to three significant figures As a result, which Buddhist ideas did he create to get rid of suffering?A) The Koran B) The Cycle of LifeC) The Laws of KarmaD) The Four Noble Truths who had all the wealth in the Middle Ages? aaAnswer any three of the following questions.3x3=Why does the acute sense of hearing later become unbearable andlead the narrator to confess his crime? (The Tell-Tale Heart) Monkeys exposed to cyanide lost consciousness at ____ parts per million (ppm) What does the slang word ''OTP'' mean? I need help with this plz help me Use the empirical rule to answer the following question. in an experiment, 200 runners were asked to run for 6 minutes on a treadmill. their heart rates after 6 minutes were normally distributed, with a mean of 110 bpm and a standard deviation of 10 bpm. a. what percent of the runners had heart rates between 100 and 120 bpm? b. what percent of the runners had heart rates between 110 and 130 bpm? c. what percent of the runners had heart rates over 90 bpm? which of the following are high-energy people who enjoy handling every detail of their own businesses? pressure due to a heel of the pointed shoe is greater than the pressure of the elphant legs when heavy extrication tools are required to force a damaged door open, you should: How many 2-digit special numbers are there?. which of the following will copy the contents of register t1 to register t0? group of answer choices lw $t1, 0($t0) lw $t0, 0($t1) sw $t1, 0($t0) sw $t0, 0($t1) move $t0, $t1 move $t1, $t0 Albert walks home from school 5 days a week he walked a total of 4 1/6 miles how far did Albert walk each day how do self schemas influence the processing of info about the self and others? Suppose that you just bought a four-year $1,000 coupon bond with a coupon rate of 6 2% when the market interest rate is 6.2%. You sell the bond one year later after the market interest rate falls to 4.2% The rate of return earned on the bond during the year was%. (Round your response to two decimal places) Solve the following inequality.20 < 8 1) How much would you have to invest in an account earning 8% interest compounded continuously, for it to be worth one million dollars in 30 years?