Answer:
because of energy difference between (n1)d and ns orbitals (sub levels) and involvement of both orbital in bond formation
Explaination:
the reason is that there is a difference in energy of orbitals of an atom of transition metal, so there (n1)d orbitals and there ns orbitals both make a bond and for this purpose they lose an electron that is why both sublevels shows different oxidation state.
Hope this helped you
Transition metals have multiple oxidation states because of their partially filled orbitals . Thus option b is correct.
What are transition metals?Transition metals are defined as essentially, a configuration attended by reactants during complex formation, as well as the reaction coordinates.
It can also be defined as a very short-lived atomic configuration at a reaction-energy diagram's local energy maximum.
Transition metals are best defined as an element with a partially filled d sub-shell on its atom or that can give rise to cations with an incomplete d sub-shell.
Transition state is defined as a chemical reaction is defined as a certain configuration along the reaction coordinate.
Oxidation state is defined as the total number of electrons that have been deleted or added to an element.
It can also be defined as an atom's charge if all of its links to other atoms were entirely ionic.
Thus, transition metals have multiple oxidation states because of their partially filled orbitals . Thus option b is correct.
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Response Sheet-Investigation 5
A group of young students looked at the oak trees in a local park.
They wondered this question. Giant oak trees grow from tiny acorns,
so where do all of their wood, bark, and leaves come from?
One student explained, "Once the acorn sprouted in the ground, the
plant grew so big from minerals and nutrients in the soil."
Another student said, "I think the plant's mass came from the food
it ate."
What would you say to these students?
A group of young students looked at the oak trees in a local park.
They wondered this question. Giant oak trees grow from tiny acorns,
so where do all of their wood, bark, and leaves come from?
One student explained, "Once the acorn sprouted in the ground, the
plant grew so big from minerals and nutrients in the soil."
Another student said, "I think the plant's mass came from the food
it ate."
What would you say to these students?
First, I will tell the students that oak trees do indeed grow from tiny acorns (nut), seeds, or stem cuttings.
Then, I will go ahead to explain to them how they grow so big with their wood, bark, and leaves.
The seeds first sprout from the acorn by utilizing the food reserves in the seed's embryo for its metabolismOnce the acorn sprouts, the root takes up mineral, nutrient, and water from the soil and these materials are used by seed cotyledons to manufacture food via photosynthesismanufactured foods are utilized to build the plant's body, including increase in the number of leaves, girths, barks, and woods.More on the oak plant can be found here: https://brainly.com/question/22999577
hydrates Question 7 of 10 Which two molecules do green plants use to make glucose?
Green plants use two molecules, carbon dioxide (CO₂) and water (H₂O), to make glucose through the process of photosynthesis.
During photosynthesis, plants capture energy from sunlight and convert it into chemical energy stored in glucose. The process occurs in the chloroplasts, which contain the pigment chlorophyll that gives plants their green color. Carbon dioxide is obtained from the atmosphere through tiny openings in the plant's leaves called stomata.
Water is absorbed by the roots and transported to the leaves through specialized tissues called xylem. In the first stage of photosynthesis, known as the light-dependent reactions, light energy is absorbed by chlorophyll, which triggers a series of chemical reactions that produce energy-rich molecules like ATP (adenosine triphosphate) and NADPH (nicotinamide adenine dinucleotide phosphate).
These energy carriers are then utilized in the next stage. In the second stage, called the light-independent reactions or the Calvin cycle, carbon dioxide from the atmosphere enters the leaf and combines with the energy-rich molecules ATP and NADPH.
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How many grams of oxygen gas would be needed to react completely with 9.76 moles of iron according to the equation below? Please round your answer to two digits after the decimal point and don't forget units and substance! Fe + O2 --> Fe2O3
Fe + O₂ → Fe₂O₃
19.52 moles of oxygen gas would be needed to react completely with 9.76 moles of iron according to the equation.
What is oxygen gas?Oxygen gas is a form of oxygen (O2) that exists as a gas at standard temperature and pressure. It is an important component of the Earth's atmosphere, making up 21% of the air we breathe.
Oxygen is produced by photosynthesis in plants and by the process of respiration in animals. In addition, oxygen is used in many industrial processes, such as welding and other forms of combustion. Oxygen is also used in medical applications, such as in oxygen therapy and in medical devices such as ventilators.
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The quantity of grams of oxygen gas that will be needed to react completely with 9.76 moles of iron according to the equation above would be = 624.64g
How to calculate the quantity of carbon?From the above equation;
1 mole of Fe reacted with 2 moles of oxygen
9.76 moles of Fe would react with X moles of oxygen.
That is;
1 mole Fe = 2 moles oxygen
9.76 mole Fe = X moles of oxygen
Make X the subject of formula;
x = 9.76× 2
X = 19.52 moles of oxygen.
But 1 mole of oxygen = 32 g
19.52 moles = X
Make X the subject of formula:
X = 32×19.52 = 624.64g.
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glycoconjugate molecule may include a carbohydrate as well as: a saccharide. an amino acid. an amino acid, a lipid, and a saccharide. a lipid. both an amino acid and a lipid.
A glycoconjugate molecule may include a carbohydrate as well as an B: "amino acid, a lipid, and a saccharide."
A glycoconjugate molecule is a complex molecule that consists of a carbohydrate component along with other molecular components. These other components can include amino acids, lipids, and saccharides. Amino acids are the building blocks of proteins, while lipids are a diverse group of molecules that include fats and oils. Saccharides, also known as sugars, are carbohydrates.
Therefore, a glycoconjugate molecule can have multiple components, including a carbohydrate (saccharide), an amino acid, and a lipid. This combination of components allows for diverse functions and biological activities of glycoconjugates in various cellular processes.
Option B is answer.
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Answer: Both an amino acid and a lipid.
Explanation: I tried the answer that was provided (that included a saccharide) and I got it wrong.
A particular reactant decomposes with a half‑life of 147 s when its initial concentration is 0.252 m. the same reactant decomposes with a half‑life of 237 s when its initial concentration is 0.156 m. Calculate the rate constant (k) and reaction order?
The rate constant (k) is approximately 0.00471 s⁻¹, and the reaction order (n) is approximately 1.64.
To determine the rate constant (k) and reaction order, we can use the relationship between the half-life and the rate constant for a first-order reaction. The half-life \((t_{1/2})\) of a first-order reaction is related to the rate constant (k) as follows:
\(t_{1/2\) = (0.693 / k)
Let's first calculate the rate constant (k) for each given half-life:
For the first half-life (\(t_{1/2\) = 147 s) and initial concentration (0.252 M):
147 s = (0.693 / k₁)
k1 = 0.693 / 147 s
k1 ≈ 0.00471 s⁻¹
For the second half-life (\(t_{1/2\) = 237 s) and initial concentration (0.156 M):
237 s = (0.693 / k2)
k₂ = 0.693 / 237 s
k₂ ≈ 0.00292 s⁻¹
Next, let's calculate the reaction order by comparing the rate constants for the two different concentrations. The reaction order (n) can be determined using the following equation:
k₁ / k₂ = (C₂ / C₁)\(^{(n-1)\)
Where C₁ and C₂ are the initial concentrations, and n is the reaction order.
Using the given concentrations (C₁ = 0.252 M and C₂ = 0.156 M), we have:
(k₁ / k₂) = (0.156 M / 0.252 M)\(^{(n-1)\)
(0.00471 s⁻¹) / (0.00292 s⁻¹) = (0.156 M / 0.252 M)\(^{(n-1)\)
Simplifying the equation:
1.61 ≈ (0.6190)\(^{(n-1)\)
To solve for n, we can take the natural logarithm (ln) of both sides:
ln(1.61) ≈ ln(0.6190)\(^{(n-1)\)
ln(1.61) ≈ (n-1) * ln(0.6190)
Using a calculator, we find:
n ≈ 1.64
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4 NH3 + 7 O2 → 4 NO2 + 6 H2O What is the mole ratio between oxygen and nitrogen dioxide? 7 moles to 6 moles 4 moles to 6 moles 7 moles to 4 moles 4 moles to 4 moles
Answer:
7:4
Explanation:
O2 : NO2
7 : 4
hope this helps :)
If the following elements were involved in a chemical reaction, which one would be most likely to form a cation?
O nitrogen (N)
potassium (K)
Ofluorine (F)
Ochlorine (CI)
Among elements that are involved in a chemical reaction, one that would be most likely to form a cation is : potassium (K)
Why potassium is cation?In the periodic table, potassium is one of the alkali metals which has a single valence electron in the outer electron shell. This valence electron is easily removed to create an ion with a positive charge that is a cation.
Halogens always form anions whereas alkali metals and alkaline earth metals form cations.
Cl- is an example of anion as Cl- atom is a chlorine atom that has gained one electron and has a negative charge of -1 since it has a full outer shell. A negatively charged ion fluorine is an anion.
Nitrogen is neither a cation nor an anion as it falls in the category of atom and atoms are electrically neutral.
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An organ system is formed by..
A) two or more cells working together.
B) two or more tissues working together.
C) two or more organs working together.
D) two or more organisms working together
which chemical equation represents a redox reaction?
Answer:
B if i'm not mistaken.
Explanation:
A procedural change in this expenment would be required it a student wanted to determine the acidity of tomato juice by titrating a juice sample with NaOH solution. Briefly explain
A. Tomato juice has a red color, making it hard to notice the color change when equivalence point is reached. A different color indicator will be needed to titrate tomato juice.
B. Tomato juice contains pulp. A filtration is necessary to remove the pulp.
C. Both A and B are correct.
D. Neither A nor B is correct.
To determine the acidity of tomato juice by titrating with NaOH solution, a different color indicator will be needed to overcome the issue of tomato juice's red color and make it easier to notice the color change when the equivalence point is reached.
When performing a titration to determine the acidity of a substance, it is important to be able to accurately detect the endpoint or equivalence point, which is when the acid and base have neutralized each other. However, tomato juice's red color can make it difficult to detect the color change associated with the endpoint.
Therefore, a different color indicator that is visible in the presence of red color needs to be used. Additionally, tomato juice contains pulp, which can interfere with the titration process and produce inaccurate results. To avoid this, filtration to remove the pulp from the juice sample is necessary before titration.
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Nuclear fission occurs when _______________ a. TNT and plutonium are combined, causing the molecules to separate. b. a nucleus breaks up into two equal fragments that release and separate more atoms. c. like atoms collide to create double nuclei. d. trinitite is created by multiple molecules that form a single atom.
Nuclear fission occurs when a nucleus breaks up into two equal fragments that release and separate more atoms. So, the correct option is B.
Nuclear fission is a process in which the nucleus of an atom breaks apart into two or more smaller nuclei. This process releases a significant amount of energy.
Option B accurately describes the process of nuclear fission. When a heavy nucleus, such as uranium-235 or plutonium-239, absorbs a neutron, it becomes unstable and splits into two smaller nuclei.These smaller nuclei, along with additional neutrons, are released in the process. The release of neutrons can trigger a chain reaction, where each neutron released can potentially collide with other nuclei, causing them to undergo fission as well.The energy released during nuclear fission is due to the conversion of a small amount of mass into a large amount of energy, as described by Einstein's famous equation, E=mc².This energy is utilized in various applications, including nuclear power generation and nuclear weapons. Nuclear fission reactions are carefully controlled in nuclear power plants to ensure the sustained release of energy without leading to uncontrolled chain reactions. Hence the correct option is B.
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What is the pOH of a solution with [OH-] = 1.4 x 10-13?
O A. -13.15
B. 14.00
C. 12.85
D. 13.15
Answer:
C. 12.85
Explanation:
just did
Balance the following
equation.
_FeO + _PdF₂ → _FeF₂ +_PdO.
Answer:
1,1,1,1
Explanation:
Can Individual atoms be moved and rearranged ?
Answer:
Yes
Explanation:
Scientists using the latest microscopic technology have found they can move individual atoms around a surface at will, a breakthrough that could have profound implications in the ultra-small world of electronics and even in industry
PLEASE, PLEASE HELP ME!!!
4 Fe + 3 02 --------------- 2 Fe2 O3
In this chemical equation, why is the number of atoms the same on each side of the arrow?
Chemical reactions reduce matter but create energy.
Chemical reactions produce new matter.
Matter cannot be created or destroyed.
Answer:
Matter cannot be created or destroyed.
Explanation:
According to law of conservation of matter, Matter can neither be created nor destroyed. It just gets converted into other forms.
So, It's important to equalize the no. of moles on either side of the chemical reaction.
\(\rule[225]{225}{2}\)
Hope this helped!
~AnonymousHelper180755) Give the name for KHSO3.A) monopotassium bisulfideB) monopotassium bisulfateC) potassium bisulfateD) potassium bisulfiteE) potassium bisulfide
The name for KHSO₃ is D) potassium bisulfite.
The elements potassium (K), hydrogen (H), sulphur (S), and oxygen (O) make up the chemical compound KHSO₃. One potassium ion (K+) and one hydrogen sulfite ion (HSO3-) are represented by its chemical formula.
This compound's naming follows inorganic chemistry norms. The term "bisulfite" in the compound's name denotes the existence of the hydrogen sulfite ion, while the prefix "potassium" denotes the presence of the potassium ion.
The name's prefix "bi-" denotes the presence of two hydrogen atoms bound to the sulfite ion in the molecule. One Sulphur atom, three oxygen atoms, and one hydrogen ion combine to form the sulfite ion, which has a -1 charge.
Potassium bisulfite is the proper name for KHSO₃ since it appropriately describes the ion makeup and charge of the molecule.
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what pair of elements will react more violently
a chlorine and lithium
b chlorine amd potassium
c iodine and lithium
d iodine and potassium
Answer:
chlorine and potassium
Explanation:
Answer:
Chlorine and potassium
What are four unusual properties of water that are a direct result of hydrogen bonding
Answer:
The following are the four unusual characteristics of water due to hydrogen bonding:
1. Water exhibits high specific heat as the presence of hydrogen bonds enhances the concentration of energy needed for the molecules to accelerate the speed, thus, elevating the specific heat.
2. Water has both high melting and high boiling points as hydrogen bonds enhance the energy, which is needed at the time of phase change, thus, increasing both the melting and the boiling points.
3. The hydrogen bonds present in the water gives rise to robust intermolecular attractions, therefore, enhancing the surface tension.
4. The hydrogen bonds present in the water makes the water to exhibit high heat of vaporization, that is, of about 41 KJ/mol.
Answer:
High boiling and melting points: Hydrogen bonds increase the amount of energy required for phase changes to occur, thereby raising the boiling and melting points.
High specific heat: Hydrogen bonds increase the amount of energy required for molecules to increase in speed, thereby raising the specific heat.
Lower density as a solid than as a liquid: Hydrogen bonds increase the volume of the solid by holding molecules apart, thereby decreasing the density.
High surface tension: Hydrogen bonds produce strong intermolecular attractions, which increase surface tension.
pbbr2 pbbr2; molar solubility == 1.05×10−21.05×10−2 mm
The given information indicates that the molar solubility of PbBr₂ is 1.05×10⁻² mm. This means that at equilibrium, the concentration of Pb²⁺ and Br⁻ ions in a saturated solution of PbBr₂ is equal to this value. The PbBr₂ compound has a very low solubility, as indicated by the small value of the molar solubility constant.
To calculate the solubility product constant (Ksp) of PbBr₂, follow these steps:
1. Write the balanced dissolution reaction: PbBr₂ (s) ⇌ Pb²⁺ (aq) + 2Br⁻ (aq)
2. Write the expression for the solubility product constant, Ksp: Ksp = [Pb²⁺][Br⁻]^2
3. Determine the molar concentrations of Pb²⁺ and Br⁻ at equilibrium based on the given molar solubility. Since the dissolution reaction shows 1 mole of PbBr₂ produces 1 mole of Pb²⁺ and 2 moles of Br⁻:
[Pb²⁺] = 1.05×10^−2 M
[Br⁻] = 2 × 1.05×10^−2 M = 2.1×10^−2 M
4. Substitute the equilibrium concentrations into the Ksp expression:
Ksp = (1.05×10^−2)(2.1×10^−2)^2
5. Calculate Ksp:
Ksp ≈ 4.63×10^−6
So, the Ksp for PbBr₂ is approximately 4.63×10^−6, given a molar solubility of 1.05×10^−2 mm.
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I NEED HELP ASAP!! DO IN A HOUR!! POEASE HELP!!A scientist views different objects using a light microscope. Which features
would the scientist MOST LIKELY see for samples from multicellular organisms?
Select the three correct answers.
small organelle features
cells organized into tissues
large cell size
different types of cells
smaller number of cells
The features that should the scientist most likely see for the samples from the multicellular organisms should contain different types of cells, Small organelle features, and a smaller number of cells.
What are multicellular organisms?It is considered as the tissue, organ or organism that should be made up of various cells that treated as multicellular. The example involved the animals, plants, and fungi also they have the specialization of distinct cells for many functions.
Therefore, The features that should the scientist most likely see for the samples from the multicellular organisms should contain different types of cells, Small organelle features, and a smaller number of cells.
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what is a mixture of elements and compounds
The substance in the image above would be classified as a mixture of elements (option E).
What is a compound and mixture?A compound is a substance formed by chemical bonding of two or more elements in definite proportions by weight.
On the other hand, a mixture is made when two or more substances are combined, but they are not combined chemically.
According to this question, an image is shown with two different substances or elements as distinguished by coloration (white and purple). These elements are combined but not chemically bonded, hence, is a mixture.
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how long did your addition of the acid mixture take? how much ethanol did you use for the recrystallization? what did your nitroacetanilide crystals look like? how long did you dry the final solid before taking the mass and melting point?
Recrystallization ; 25 mL of solvent are needed at 100 oC to dissolve 100 mg of the chemical. 75 mg of the chemical will precipitate at 0 oC while 25 mg will remain in solution.
what did your nitroacetanilide crystals look like? how long did you dry the final solid before taking the mass and melting point?The chemical compound para nitroacetanilide, commonly known as 4-nitroacetanilide, is a nitroacetanilide derivative made from acetanilide and a nitrating combination. A trace of ortho product also forms along with the para product.
Through nitration, the chemical molecule p-nitroacetanilide is created from acetanilide. P-nitroacetanilide is created when acetanilide is treated with a nitrating mixture, which is a combination of nitric acid and sulfuric acid. O-nitroacetanilide is also generated as a small byproduct along with p-nitroacetanilide. It is quite simple to separate p-nitroacetanilide through crystallization since o-nitroacetanilide is highly soluble in alcohol.
Because ethanol is endlessly cosoluble with water and has high dissolving properties for many organics, ethanol and water mixtures are frequently utilized. Many organic compounds' solubilities can be drastically and quickly decreased by the addition of water, which can cause crystallization.
The solution may become too diluted for crystals to form if you add too much solvent. The flask needs to be gently cooled, first at room temperature and then in cold water. Impurities will be captured by a hastily formed crystal's lattice. Smaller crystals will be produced as a result.
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A projectile moves horizontally with ____?____motion
HELP PLEASE
Answer:
hi
Explanation:
hi
What is the purpose of adding base in the aldol condensation reaction?.
The purpose of adding base in the aldol condensation reaction is to generate the enolate ion, which is a strong nucleophile and is critical for the reaction to take place. The enolate ion attacks the carbonyl group of another molecule, resulting in the formation of a carbon-carbon bond.
In the aldol condensation reaction, the base serves two primary functions. Firstly, it generates the enolate ion, which is an essential intermediate for the reaction. Secondly, the base helps to remove the alpha hydrogen atom from the carbonyl compound, allowing it to become acidic and therefore more susceptible to the removal of the proton. When the base is added to the carbonyl compound, it accepts a proton to form an anion. This anion then attacks the carbonyl group of another molecule, resulting in the formation of a carbon-carbon bond. As a result, the aldol product is formed. The product can either be an α,β-unsaturated carbonyl compound or a β-hydroxy carbonyl compound depending on the reaction conditions.
In summary, the addition of base in the aldol condensation reaction serves to generate the enolate ion, which is a strong nucleophile and is essential for the reaction to occur. It also helps to remove the alpha hydrogen atom from the carbonyl compound, allowing it to become acidic and more reactive.
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If 30.0 mL of 0.150 M CaCl₂ is added to 38.5 mL of 0.100 M AgNO3, what is the mass of the AgCl precipitate?
If 30.0 mL of 0.150 M CaCl₂ is added to 38.5 mL of 0.100 M AgNO3. The mass of the AgCl precipitate is 0.552 g.
What is Stoichiometry ?Stoichiometry helps us use the balanced chemical equation to measure quantitative relationships and it is to calculate the amounts of products and reactants that are given in a reaction.
What is Balanced Chemical Equation ?The balanced chemical equation is the equation in which the number of atoms on the reactant side is equal to the number of atoms on the product side in an equation.
Now we have to write the balanced equation
2AgNO₃ + CaCl₂ → 2AgCl + Ca(NO₃)₂
Molecular Weight of CaCl₂ = 110.98 g/mol
Molecular Weight of AgNO₃ = 170.01 g/mol
Molecular Weight of AgCl = 143.45 g/mol
Here,
Volume of CaCl₂ = 30.0 mL = 0.03L
Volume of AgNO₃ = 38.5 mL = 0.0385 L
Now find the number of moles
Number of moles = Volume × Molarity
Number of moles of CaCl₂ = 0.03 L × 0.150
= 0.00456 mol
Number of moles of AgNO₃ = 0.0385 L × 0.100
= 0.00385 mol
The stoichiometric ratio of AgNO₃ to CaCl₂ is 2:1.
= \(\frac{0.00385}{2}\)
= 0.001925 mol
According to Stoichiometry Mass of AgCl
\(= 0.0385 \times \frac{0.1}{1\ \text{mol}} \times \frac{2\ \text{mol} AgCl}{2\ \text{mol} AgNO_3} \times \frac{143.4\ g}{1\ \text{mol}}\)
= 0.552 g AgCl
Thus from the above conclusion we can say that If 30.0 mL of 0.150 M CaCl₂ is added to 38.5 mL of 0.100 M AgNO3. The mass of the AgCl precipitate is 0.552 g.
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given the pka of each acid, determine whether it is strong or weak.
The answer to the given question about strong acid and weak acid is weak, strong, weak, strong.
Based on how strongly or weakly they ionize in water, acids are categorized as either strong or weak. An acid that is totally ionized in an aqueous solution is referred to be a strong acid. In water, hydrogen chloride (HCl) totally ionizes into hydrogen and chloride ions. An acid that ionizes very little in an aqueous solution is said to be weak. Acetic acid is a highly popular weak acid that can be found in vinegar. Acetic acid's incomplete ionization is indicated in the equation by the double arrow. Weak acids ionize to varying degrees, but often less than 10%. Since just 1.3% of the acetic acid in a 0.10M solution gets ionized, the equilibrium greatly favors the reactants.
Given That:
Acetic acid, pKa = 4.7
This above solution is Weak.
Nitric acid, pKa = -2
The above solution is strong.
Citric acid, pKa = 3.1
The above solution is weak
Sulfuric acid, pKa = -5
The above solution is strong.
Complete Question
Given the pKa of each acid, determine whether it is strong or weak.
acetic acid, pKa=4.7 ___
nitric acid, pKa=-2 ____
citric acid, pKa=3.1 ___
sulfuric acid, pKa=-5 ___
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Determine the molecular formula for a compound that contains 89.94% C and the rest H, when the molecular mass is 120.2 amu.
Answer:
C9H9
Explanation:
C. H
89.94. 10.06
divide each by their mass number89.94/12. 10.06/1
7.495. 10.06
divide both by smallest7.495/7.495. 10.06/7.495
1. :. 1
empirical formula=CH
(CH)n=120.2
(12+1)n=120.2
13n=120.2
n=120.2/13
n=9.
molecular formula=C9H9
which gas sample has the greater mass
Answer:
what are the gas samples
why do we say the partials in a rock lying on the ground have kinetic energy and potential energy
Answer:
All particles of matter are always in constant motion. In this case, the particles of the rock possess kinetic energy as they vibrate in place. However, the particles also contain potential energy due to their position and arrangement. This form of stored energy is responsible for keeping the particles bonded together.
Explanation:
which substances are composed of the same monomer units, just arranged differently?
Cellulose and Starch substances are composed of the same monomer units, just arranged differently.
Option D is correct.
What is monomer the littlest unit?A monomer is a little particle that responds with a comparative atom to frame a bigger atom. It is the littlest unit in a polymer, which is much of the time a macromolecule with high sub-atomic weight. DNA, RNA, proteins, and carbohydrates are all biological macromolecules made up of monomers.
What is Monomer application?Some cracks can be successfully repaired with monomer systems. A liquid composed of monomers that will polymerize into a solid is known as a monomer system. The flammability, toxicity, and volatility of suitable monomers vary. They are insoluble in water.
Incomplete question:
Which substances are composed of the same monomer units, just arranged differently?
a. saccharides; glycogen
b. glycogen; chitin
c. cellulose; chitin
d. cellulose; starch
e. starch; sugar
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