The synthesis of dibenzalacetone can be achieved through a base-catalyzed aldol condensation reaction between two molecules of benzaldehyde and one molecule of acetone.
The reaction mechanism involves the formation of reactive intermediates such as enolate ions and alpha-beta unsaturated carbonyl compounds.
Initially, the acetone is deprotonated by a base such as sodium hydroxide to form an enolate ion. The benzaldehyde also undergoes deprotonation to form a benzyl anion. The enolate ion then attacks the benzyl anion to form an alpha-beta unsaturated carbonyl compound known as benzylideneacetone.
The benzylideneacetone molecule can then undergo another aldol condensation reaction with another molecule of benzaldehyde, to form the final product dibenzalacetone. The reaction mechanism involves the formation of reactive intermediates such as enolate ions and alpha-beta unsaturated carbonyl compounds.
The major product formed in this reaction is dibenzalacetone, while the minor product formed is benzylideneacetone. The mechanism for the formation of dibenzalacetone involves the intermediate formation of benzylideneacetone, which subsequently undergoes another aldol condensation reaction with benzaldehyde to form the final product.
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the rate constant of a first order decomposition reaction is 0.0147s. if the initial concentration of reactant is 0.178m, what is the concentration of reactant after 30 seconds
The concentration of the reactant after 30 seconds is 0.109 M. In a first-order decomposition reaction, the rate of the reaction depends only on the concentration of the reactant.
The rate constant (k) for a first-order reaction is a constant that describes the proportionality between the rate of the reaction and the concentration of the reactant. The equation for a first-order reaction is ln([A]t/[A]0) = -kt, where [A]t is the concentration of the reactant at time t, [A]0 is the initial concentration of the reactant, k is the rate constant, and t is time.
In this case, we are given the rate constant (k) of 0.0147 s^-1 and the initial concentration of reactant ([A]0) of 0.178 M. We are asked to find the concentration of reactant ([A]t) after 30 seconds (t=30). Plugging these values into the first-order equation, we get:
ln([A]t/0.178) = -0.0147 x 30
ln([A]t/0.178) = -0.441
[A]t/0.178 = e^-0.441
[A]t = 0.178 x e^-0.441
[A]t = 0.109 M
Therefore, the concentration of the reactant after 30 seconds is 0.109 M.
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which of the following is a pure compound A. ethanol B. petrol C. steel D. tap water
Answer:
D. tap water
keep on learning!
Answer: ethanol
Explanation: as it is a pure compound and can sometimes be a mixture while all the rest are mixtures.
2) Why do some earthquakes cause more damage than others?
Answer:
Earthquakes are more intense the faster the planet's crust slams together, which explains why the shaking causes so much damage in some of the most populated areas around mountain chains. ... One reason for this connection is that when two plates come together quickly, the area over which an earthquake occurs is larger.Explanation:
How do the farmers use the property of density of cranberries to harvest the crop?
Josh decided to investigate the effect of the reagents listed in part b of the lab on the cobalt chloride system described on page 60 of the lab manual. Their cobalt chloride solution composed of 0. 20 m cocl2 in 4. 0 m nacl. Identify one reaction they would have observed that to push the reaction either in the forward or reverse direction by filling in the blanks in the statement given below. Identify what phenomenon occurred that caused the equilibrium to shift.
One of the reactions they would have observed that would push the reaction either in the forward or reverse direction is NaCl (aq) ⇌ Na+ (aq) + Cl- (aq)
Cobalt chloride system described on page 60 of the lab manual consist of cobalt chloride solution containing 0.20 M CoCl2 in 4.0 M NaCl. When one of the reagents listed in part b of the lab is added, there will be a change in the reaction system and this will push the reaction either in the forward or reverse direction.Reaction that would push the reaction either in the forward or reverse direction by filling in the blanks in the statement given below is shown below;NaCl (aq) ⇌ Na+ (aq) + Cl- (aq)When a small quantity of NaCl is added to the Cobalt chloride solution, the concentration of Cl- ions increases. According to Le Chatelier's principle, the equilibrium will shift towards the left in order to counteract the increase in Cl- ions. This is because by reducing the amount of Cl-, the equilibrium system will try to balance the added NaCl. So, the phenomenon that occurred that caused the equilibrium to shift was the addition of NaCl to the cobalt chloride solution.
Therefore, we can say that the addition of NaCl to the cobalt chloride system described on page 60 of the lab manual will cause the equilibrium to shift towards the left.
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Be specific and shorten it in ur own words I’ll brainlist and rate u 5 star! :)
What are the 2 major steps involved in the breakdown of glucose to carbon dioxide; cellular respiration? Explain what happens in each step.
Glycolysis, the splitting of glucose into two 3-carbon molecules.
The citric acid or Krebs cycle, which produces CO2, NADH, FADH2, and ATP.
What would be the concentration of hydroxide ions in a solution made by
dissolving 10.0 g of sodium hydroxide in a solution with a final volume of
150.0 mL
The concentration of hydroxide ions in the solution is also 1.67 M.
What is stoichiometric ratio?To determine the concentration of hydroxide ions in the solution, we need to first calculate the number of moles of sodium hydroxide (NaOH) present in the solution, and then use stoichiometry to determine the concentration of hydroxide ions.
The formula for sodium hydroxide is NaOH, which contains one sodium ion (Na+) and one hydroxide ion (OH-). The molar mass of NaOH is 40.00 g/mol (sodium: 22.99 g/mol, oxygen: 15.99 g/mol, hydrogen: 1.01 g/mol).
First, we need to convert the mass of NaOH to moles:
moles of NaOH = mass of NaOH / molar mass of NaOH
moles of NaOH = 10.0 g / 40.00 g/mol
moles of NaOH = 0.250 mol
Next, we need to calculate the final concentration of NaOH in the solution:
concentration of NaOH = moles of NaOH / volume of solution
concentration of NaOH = 0.250 mol / 0.150 L
concentration of NaOH = 1.67 M
Since sodium hydroxide is a strong base, it completely dissociates in water to produce one mole of hydroxide ions for every mole of sodium hydroxide:
NaOH(s) → Na+(aq) + OH-(aq)
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4- The equilibrium constant for the reaction A (g) B (g) is 10. A reaction mixture initially contains [A]
The initial concentration in the reaction mixture will contain [A] = 0.1 M and [B] = 1.0 M
Below is the reaction
A(g) → B(g)
And the equilibium constant will be explained in terms of [A] and [B]:
Keq = 10 = [B]/[A]
If the first conditions are that [A] = 1.1 M and [B] = 0.0 M, the conditions at equilibrium is:
[A] = 1.1M - x
[B] = 0.0M + x
Now we rewrite Keq:
Keq = 10 = [0.0 +x] / [1.1 -x]
at the end we got it for x:
10 = [0.0 +x] / [1.1 -x]
10 * (1.1-x) = x
11 - 10x = x
11 = 11x
x = 1
equilibrium, the concentrations are:
[A] = 1.1 M - 1 = 0.1 M
[B] = 0.0 M + 1 = 1.0 M
Thus, the concentration of A is 0.1 M and the concentration of B is 1M.
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How to balance this equation
NaCl +
F₂ →
NaF +
Cl₂
Answer:
The balanced equation is:
2NaCl + F₂ → 2NaF + Cl₂
Explanation:
Balancing an equation is a bit like playing musical chairs. There is no quick formula for success, but a little trial and error will lead to the solution. And a little practice goes a long way.
NaCl + F₂ → NaF + Cl₂
Check how many times an element appears on each side of the equation:
Element Reactants Products Balanced?
Na 1 1 Yes
Cl 1 2 No
F 2 1 No
The equation has two elements not balanced. Lets start with the Cl. Each molecule of Cl2 has 2 Cl atoms, but there is only 1 brought in by the NaCl. We can't use Cl as a product, since it does not exist under normal conditions. So lets make the coefficient for the NaCl 2, instead of 1.
2NaCl + F₂ → NaF + Cl₂
Element Reactants Products Balanced?
Na 2 1 No
Cl 2 2 Yes
F 2 1 No
Now the sodium is unbalanced due to this change. Add a coefficient of 2 to the NaF to accomodate the extra sodium atom:
2NaCl + F₂ → 2NaF + Cl₂
Element Reactants Products Balanced?
Na 2 2 Yes
Cl 2 2 Yes
F 2 2 Yes
The equation is now balanced. Each atom can be accounted for.
2NaCl + F₂ → 2NaF + Cl₂
====
This process may seem a bit tedius, but it becomes easier with practice: Some points that can help:
Use pencil and paper. Be prepared to try/erase the options.Look for the most "difficult" or complex moplecule first and assign a coefficent of 1 just to get started. Each molecule must be a whole number in the final equation.Although the final equation needs to have whole numbers, there is nothing wrong with fractions to start the process. For the example above, instead of doubling the NaCl, add a (1/2) as the Cl2 coefficient:NaCl + F₂ → NaF + (1/2)Cl₂
Element Reactants Products Balanced?
Na 1 1 Yes
Cl 1 2 Yes
F 2 1 No
Now do the same for the F2 on the reactant side:
NaCl + (1/2)F₂ → NaF + (1/2)Cl₂
Element Reactants Products Balanced?
Na 1 1 Yes
Cl 1 2 Yes
F 2 2 Yes
The equation is now balanced. But there is no such thng as 1/2 of a molecule (except, perhaps, in politics).
So multiply all the coefficients by a facor that makes them whole numbers. We can use 2, in this case.
2NaCl + 2(1/2)F₂ → 2NaF + 2(1/2)Cl₂
2NaCl + 1F₂ → 2NaF + 1Cl₂
This is the correct equation. The point is that a non-whole coefficient may be used to start, as long as they are all whole numbers at the conclusion.
a sample of gas occupies a volume of 70.3 ml . as it expands, it does 140.6 j of work on its surroundings at a constant pressure of 783 torr . what is the final volume of the gas?
A sample of gas occupies a volume of 70.3 ml as it expands, it does 140.6 j of work on its surroundings at a constant pressure of 783 torr and the final volume of the gas is 11.12L
A gas is a sample of matter that conforms to the shape of a container in which it is held and acquires a uniform density inside the container and even in the presence of gravity and regardless of the amount of substance in the container
Here given data is 11.12L
V₁ = Initial volume = 70.3 ml = 0.0703ml = (1L=1000ml)
w = 140.6 J = 1.387 J = (1Latm=101.3J)
Pressure = 783 torr = 1.03 atm = (1atm=760 torr)
V₂ = final volume = ?
1.387Latm = 1.03 atm × (V₂ - 0.0703ml)
(V₂ - 0.0703ml) = 11.05
V₂ = 11.12L
The final volume of the gas is 11.12L
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Indium has two naturally occurring isotopes: indium-113 and indium-115. The relative atomic mass of indium is 114.82. Calculate the natural abundance of each isotope.
Answer:
114.818 amu.x(112.9041) + (1 - x)
(114.9039) = 114.818Solving for xx=0.043 or 4.3%
Explanation:
The average atomic mass written in the periodic table is determined from the relative abundances of the element's isotopes. The equation would be:Average Atomic Mass = ∑(Relative Abundance×Mass)Let be the relative abundance of Indium-113. Because there are only 2 isotopes, their relative abundances should equal to 1, such that the relative abundance for Indium-15 is (1-x). The atomic mass of indium is 114.818 amu.x(112.9041) + (1 - x)(114.9039) = 114.818Solving for x,x = 0.043 or 4.3%
PLEASEE HELP IM DESPERATE
You'll have 20.5 g of hydrochloric acid (HCl) left, which is the answer to your query.
The least amount of hydrochloric acid that can be produced?Data
HCl = 31.4 g
NaOH = 12 g
insufficient HCl =?
equilibrium in a chemical reaction
NaCl and H2O are produced from HCl and NaOH.
HCl's molar mass is equal to 1 + 35.5 = 36.5 g.
NaOH's molar mass is 40 g (23 + 16 + 1)
Figure out the limiting reactant.
Theoretical yield: 36.5/40 = 0.9125 for HCl/NaOH.
Research yield: HCl/NaOH = 31.4/12 = 2.62
Conclusion
Because of the increasing experimental yield, NaOH is the limiting reactant.
The excess reactant's mass should be determined.
35. 5 g of HCl ———————— NaOH weight 40 g
x ———————— NaOH in 12 g
x = (12 x 36.5) / 40
x = 438 / 40
x = 10.95 grams of HCl
Surplus HCl = 31.4 - 10.95
= 20.5 g
You'll have 20.5 g of HCl left, which is the answer to your query.
The complete question is,
To create aqueous sodium chloride and liquid water, aqueous hydrochloric acid must be combined with solid sodium hydroxide. Consider combining 12.g of sodium hydroxide with 31.4g of hydrochloric acid. Determine the smallest amount of hydrochloric acid that could possibly remain after the reaction. The quantity of significant digits in your response must be accurate.
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The atomic size of zirconium is smaller than
a. niobium
b. Yttrium
c. Molybdenum
d. None of the above
Answer:
b
Explanation:
because hahamaskdjdjskskskskkssksksks
When CoBr2 (aq) and Li3PO4 (aq) are mixed, which precipitate forms (if any)?1-LiBr2 -Li3Br23-CoPO44-Co3(PO4)25-No precipitate
Whenever there is a reaction between CoBr2 and LiPO4 then the precipitate that is formed will be Co3(PO4)2 so, the correct option is (4).
This is because the reaction that takes place is a double displacement reaction between CoBr2 and Li3PO4, where the Co2+ and PO43- ions exchange partners to form Co3(PO4)2 and 6LiBr:
CoBr2 + Li3PO4 -> Co3(PO4)2 + 6LiBr
Co3(PO4)2 is insoluble in water, and thus forms a precipitate. The other products, LiBr, remains in solution because they are soluble salts.
Therefore, the correct answer is option 4 - Co3(PO4)2 precipitate.
Co3(PO4)2 is a chemical compound with the formula Co3(PO4)2. It is also known as cobalt(II) phosphate, and is a grayish-white solid that is insoluble in water. It is an ionic compound that contains Co2+ and PO43- ions, and forms a crystalline lattice structure.
Co3(PO4)2 is commonly used in the production of ceramics and glass, as a catalyst in certain chemical reactions, and as a pigment in paints and coatings. It also has potential applications in the field of energy storage, particularly in the development of new battery materials.
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**NEED ASAP!!!!**
A. 1
B. 2
C. 3
D. 4
the picture is shown on the question top, asap!
Methylamine could be said to be a Brownstead Lowry base because of 3.
What is the Bronstead Lowry base?
A Brnsted-Lowry base is a type of organism or molecule with the capacity to bind to or take a proton from an acid. A base transforms into its conjugate acid when it takes a proton. This hypothesis is based on the notion that protons are transferred across species during an acid-base reaction.
In contrast to the Arrhenius theory, which defines bases as chemicals that create hydroxide ions, the Brnsted-Lowry base idea offers a broader and more encompassing definition of bases.
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what is the difference between concentrated acid and a weak one?
Answer:
Difference between concentrated acid and weak acid :---
According to Arrhenius's theory the substances which easily get dissociated into H+ ions when dissolved in water are acids.And the substance which readily gives H+ ions on dissociation (when dissolved in water) are Strong Acid. Examples are HCl , H2SO4 etc.While,
Concentration of acid is just the value of pH. pH is the measurement of concentration of acid or base. The lower the pH, higher the concentration.So strong acid is strong because it gives H+ ions readily in water and Concentration is the value of pH.You will use a filter funnel in this experiment to
A )measure pH
B) collect pieces of cabbage
C) dry pieces of cabbage
D) separate cabbage from liquid
Answer:separate cabbage from liquid
Explanation:
Just trust me lol
Answer:
Its D - separate cabbage from liquid
Explanation:
On Edge 2021
(j1-2009f-27) when a hydrate of na2co3 is heated until all the water is removed, it loses 54.3 percent of its mass. what is the formula of the hydrate?
The formula of the hydrate when 54.3% of its mass is lost upon heating is Na₂CO₃.7H₂O.
When a hydrate of Na₂CO₃ is heated until all the water is removed, it loses 54.3 percent of its mass. This means that 54.3 percent of the original mass of the hydrate was water. To determine the formula of the hydrate, we need to find the number of moles of water that were present in the original hydrate. We can do this by using the formula:
mass of water/molar mass of water = moles of water
54.3/18.015 = 3.01 moles of water
Since the molar mass of Na₂CO₃ is 105.99 g/mol, we can calculate the number of moles of Na₂CO₃ in the original hydrate:
mass of Na₂CO₃ /molar mass of Na₂CO₃ = moles of Na₂CO₃
45.7/105.99 = 0.431 moles of Na₂CO₃
Now we can determine the formula of the hydrate by dividing the moles of water by the moles of Na₂CO₃:
3.01/0.431 = 6.98 ≈ 7
Therefore, the formula of the hydrate is Na₂CO₃.7H₂O.
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enough of a monoprotic acid is dissolved in water to produce a 1.62 m solution. the ph of the resulting solution is 2.73 . calculate the ka for the acid.
The Ka for the acid is approximately 1.3 x 10⁻⁵.
How to find the value of Ka?The first step in solving this problem is to use the pH of the solution to calculate the concentration of hydronium ions, [H3O+].
pH = -log[H3O+]
2.73 = -log[H3O+]
[H3O+] = 5.0 x 10⁻³ M
Since the acid is monoprotic, the concentration of the acid is equal to the concentration of hydronium ions, [HA] = [H3O+] = 5.0 x 10⁻³ M.
The next step is to use the equilibrium expression for the dissociation of the acid to calculate the acid dissociation constant, Ka.
HA + H2O ⇌ H3O+ + A-
Ka = [H3O+][A-] / [HA]
At equilibrium, the concentration of the acid that has dissociated is equal to the initial concentration of the acid minus the concentration of the acid that remains undissociated. Since the acid is weak, we can assume that the change in concentration of the acid due to dissociation is small compared to the initial concentration of the acid.
Let x be the concentration of acid that has dissociated. Then the concentration of undissociated acid is (0.005 - x).
Substituting these values into the equilibrium expression and simplifying:
Ka = (5.0 x 10⁻³ - x)(x) / (5.0 x 10⁻³)
Since x is small compared to 5.0 x 10⁻³, we can assume that (5.0 x 10⁻³ - x) ≈ 5.0 x 10⁻³, and simplify the expression further:
Ka ≈ x² / 5.0 x 10⁻³
Ka ≈ 1.3 x 10⁻⁵
Therefore, the acid dissociation constant, Ka, for the monoprotic acid is approximately 1.3 x 10⁻⁵.
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Is calcium carbonate an acid or alkaline
Calcium carbonate is neither acid nor base, it's a SALT.
Answer:
none,It is a salt of the calcium, ion a strong base and carbonic acid, a very weak acid. Answer: calcium carbonate is a salt, it is neither acid nor base
What role do stomach enzymes play in digestion? A They transfer food out of the esophagus. B They break down food into smaller parts. C They move food down into the intestines. D They physically mix food with stomach acid.
Answer:
b
Explanation:
Answer:
b
Explanation:
b
the statue of liberty is made of copper, a reddish metal. Which of the following is a chemical property of copper that is evident in this photo?
A. It is reactive
B. It is flammable
C. It is malleable
D. It is ductile
Answer:
A. its reactive
Explanation
Task 1:
Which process involves the movement of sediment?
a. Deposition
b. Weathering
c. Erosion
d. Cementing
What is the role of youth in economy?
Answer:
The youth is the indicator of how developed a country is, and they determine how fast or slow the economy grows
Explanation:
If the youth don’t get employed, the level of poverty increases due to the constantly increasing number of youths and this means that even if the working population generates capital, on one hand, the youth will be negating its effect on the other hand, and therefore at the end of the day, there will be no significant economic growth.
Identify the properties of a covalent substance (multiple answers )
A) high melting point
B) low melting point
C) soluble in water
D) soluble in alcohol
E) conducts electricity in water
does not conduct electricity in water
solution A is 0.010 M glucose, and solution B is a 0.050 M glucose. The glucose will dialyze to the ?
Glucose will dialyze from a 0.050 M solution to a 0.010 M solution, glucose molecules will diffuse through the semipermeable membrane, from the higher concentration.
Dialysis is a process in which solute molecules selectively pass through a semipermeable membrane from a region of higher concentration to a region of lower concentration. In this scenario, glucose is the solute and solutions A and B represent different concentrations of glucose.
Since the concentration of glucose in solution B (0.050 M) is higher than in solution A (0.010 M), glucose molecules will dialyze from solution B to solution A. This movement occurs because dialysis allows for the equalization of concentrations, with solute molecules moving from regions of higher concentration to regions of lower concentration.
As a result, solution B to the lower concentration solution A, until the concentration becomes equalized or reaches equilibrium. Therefore, the glucose will dialyze from the 0.050 M solution to the 0.010 M solution.
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In an experiment between 26.4 grams of Mg and O,, Mgo is produced. The percent
yield was 90%. Determine the actual yield of magnesium oxide.
Answer:
39.6 g
Explanation:
The equation of the reaction is;
2Mg(s) + O2(g) --------> 2MgO(s)
To obtain the limiting reactant;
Number of moles in 26.4 g of Mg = 26.4g/24 g/mol = 1.1 moles
If 2 moles of Mg yields 2 moles of MgO
1.1 moles of Mg yields 1.1 * 2/2 = 1.1 moles of MgO
Number of moles in 26.4 g of O2 = 26.4 g/32g/mol = 0.825 moles
If 1 mole of O2 yields 2 moles of MgO
0.825 moles of O2 yields 0.825 moles * 2/1 = 1.65 moles of MgO
Hence Mg is the limiting reactant.
Theoretical yield of MgO = 1.1 moles of MgO * 40 g/mol = 44 g
Percent yield = 90%
Percent yield = actual yield/theoretical yield * 100
Actual yield = Percent yield * theoretical yield/100
Actual yield = 90 * 44/100
Actual yield = 39.6 g
which macromolecules has a nitrogen base and phosphate found in its structure?
Answer:
A nucleic acid
Explanation: A nucleic acid is a polymeric macromolecule made up of repeated units of monomeric 'nucleotides' composed of a nitrogenous heterocyclic base which is either a purine or pyrimidine, a pentose five-carbon sugar either ribose or 2′-deoxyribose, and one to three phosphate groups.
issued this? watch kcv: atomic theory; read section 2.3. you can click on the review link to access the section in your etext. carbon and oxygen form both carbon monoxide and carbon dioxide. when samples of these are decomposed, the carbon monoxide produces 3.36 g of oxygen and 2.52 g of carbon, while the carbon dioxide produces 9.92 g of oxygen and 3.72 g of carbon.
The atomic ratio of carbon to oxygen in carbon monoxide (CO) is 1:1, and the atomic ratio of carbon to oxygen in carbon dioxide (CO₂) is 2:1.
Firstly, we can analyze the decomposition of carbon monoxide (CO) and carbon dioxide (CO₂) to determine the atomic ratios involved.
Let's denote the atomic ratio of carbon to oxygen in carbon monoxide as x, and the atomic ratio of carbon to oxygen in carbon dioxide as y.
According to the given data;
Decomposition of carbon monoxide (CO);
Oxygen produced = 3.36 g
Carbon produced = 2.52 g
We know that the atomic mass of carbon is 12 g/mol, and the atomic mass of oxygen is 16 g/mol. Using these values, we can calculate the number of moles for each element;
Number of moles of oxygen = mass / atomic mass = 3.36 g / 16 g/mol = 0.21 mol
Number of moles of carbon = mass / atomic mass = 2.52 g / 12 g/mol = 0.21 mol
Since the atomic ratio of carbon to oxygen in carbon monoxide is x, we can write the following equation;
0.21 mol C / (0.21 mol O) = x
Simplifying the equation, we have;
x = 1
Therefore, the atomic ratio of carbon to oxygen in carbon monoxide is 1:1.
Decomposition of carbon dioxide (CO₂);
Oxygen produced = 9.92 g
Carbon produced = 3.72 g
Following the same calculations as before;
Number of moles of oxygen = mass / atomic mass = 9.92 g / 16 g/mol = 0.62 mol
Number of moles of carbon = mass / atomic mass = 3.72 g / 12 g/mol = 0.31 mol
Since the atomic ratio of carbon to oxygen in carbon dioxide is y, we can write the following equation;
0.31 mol C / (0.62 mol O) = y
Simplifying the equation, we have;
y = 0.5
Therefore, the atomic ratio of carbon to oxygen in carbon dioxide is 1:0.5, which can be simplified to 2:1.
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--The given question is incomplete, the complete question is
"Missed this? watch kcv: atomic theory; read section 2.3. you can click on the review link to access the section in your text. carbon and oxygen form both carbon monoxide and carbon dioxide. when samples of these are decomposed, the carbon monoxide produces 3.36 g of oxygen and 2.52 g of carbon, while the carbon dioxide produces 9.92 g of oxygen and 3.72 g of carbon. Calculate the atomic ratio of carbon to oxygen in carbon monoxide, and carbon dioxide."--
Ca(OH)2 is an Arrhenius ______________ and increases the concentration of __________ when added to water