van der waals strain involving alkyl groups causes the bond angle at the oxygen to be larger in ethers than in alcohols. Describe the nature of van der waals strain and why this type of strain is called van der waals strain.

Answers

Answer 1

The van der Waals strain involving alkyl groups and its effect on the bond angle at the oxygen in ethers and alcohols.

Van der Waals strain, also known as steric strain, occurs when non-bonded atoms or groups of atoms come too close to each other and experience repulsive forces due to the electron clouds surrounding them. These repulsive forces can cause a change in the bond angles and geometry of the molecule. This type of strain is called van der Waals strain because it arises from the van der Waals forces, which are weak intermolecular forces between atoms and molecules.

In ethers (R-O-R') and alcohols (R-O-H), the bond angle at the oxygen atom is influenced by the van der Waals strain involving alkyl groups. In ethers, there are two alkyl groups attached to the oxygen atom, whereas, in alcohols, there is only one alkyl group and one hydrogen atom. The alkyl groups are larger and have more electrons than hydrogen atoms, so their electron clouds experience stronger repulsive forces.

As a result, in ethers, the two alkyl groups try to stay as far away from each other as possible to minimize the van der Waals strain, causing the bond angle at the oxygen to be larger compared to that in alcohols. In contrast, the smaller size of the hydrogen atom in alcohols leads to less van der Waals strain, and therefore, a smaller bond angle at the oxygen.

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Related Questions

how much energy is needed to convert 120g of ice at -35°C to steam at 150°C?

Answers

381,840 J would be the answer

what bbolume of a 17.5 m stock soultion of acetic acid is required to prepare a 500 ml solution of 1.00 m acetic acid

Answers

Total, 28.6 mL of the 17.5 M stock solution of acetic acid is required to prepare a 500 mL solution of 1.00 M acetic acid.

To determine the volume of the 17.5 M stock solution of acetic acid required to prepare a 500 mL solution of 1.00 M acetic acid, we can use the following formula:

V₁ × C₁ = V₂ × C₂

Where; V₁ = Volume of the stock solution (in liters)

C₁ = Concentration of the stock solution (in moles per liter)

V₂ = Volume of the final solution (in liters)

C₂ = Concentration of the final solution (in moles per liter)

Converting given values to required units;

V₁ = ?

C₁ = 17.5 M

V₂ = 500 mL = 0.5 L

C₂ = 1.00 M

Now, we can plug in the values into the formula and solve for V₁

V₁ × (17.5 M) = (0.5 L) × (1.00 M)

V₁ = (0.5 L × 1.00 M) / 17.5 M

= 0.0286 L

≈ 28.6 mL

Now, we can plug in the values into the formula and solve for V₁

V₁ × (17.5 M) = (0.5 L) × (1.00 M)

V₁ = (0.5 L × 1.00 M) / 17.5 M

= 0.0286 L

≈ 28.6 mL

Therefore, approximately 28.6 mL of the 17.5 M stock solution of acetic acid is required.

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alice, a 14-year-old adolescent has been diagnosed with anorexia nervosa. which of the following would you most likely find in your assessment of alice? group of answer choices dysmenorrhea tachycardia decreased body temperature heat intolerance

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A 14-year-old adolescent girl, Alice, has been diagnosed with anorexia nervosa. In the assessment of Alice, the findings that are more commonly associated with anorexia nervosa are Dysmenorrhea, decreased body temperature, and Heat intolerance.

Dysmenorrhea: Anorexia nervosa can lead to hormonal imbalances and disruptions in the menstrual cycle, which can cause irregular or absent periods (amenorrhea) and sometimes dysmenorrhea (painful periods).

Decreased body temperature: Anorexia nervosa can lead to lower body weight and reduced body fat, which can result in a lower body temperature. This is a physiological response to conserve energy and maintain the body's functions.

Heat intolerance: Anorexia nervosa can affect the body's ability to regulate temperature properly, leading to increased sensitivity to heat or cold. Individuals with anorexia may feel more discomfort or intolerance in extreme temperatures.

Hence,  the findings that are more commonly associated with anorexia nervosa are explained above.

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Thermal energy is the energy associated with
a. electric fields
b. being stored in chemical bonds
c. the pull of gravity
d. temperature

Answers

Answer:

D is the answer

Explanation:

Because thermal is Heat Energy

I hope it's right

Thermal energy is the energy associated with temperature. The correct option is d.

Thermal energy is the energy associated with a substance's or system's temperature. It is a type of kinetic energy that results from the random motion of tiny particles.

The higher the temperature, the larger the average kinetic energy of the particles and the bigger the amount of thermal energy present.

Heat transmission, phase shifts (such as melting or boiling), and the general thermal behaviour of materials all require thermal energy.

It differs from other types of energy including electrical energy (option a), chemical potential energy (option b), and gravitational potential energy (option c).

Thus, the correct option is d.

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Your body is made up of trillions of cells that perform all the functions you need to survive. Which other kinds of organisms are composed of cells?

Only animals are composed of cells.
Only animals are composed of cells.

Only animals and plants are composed of cells.
Only animals and plants are composed of cells.

Only animals, plants, and bacteria are composed of cells.
Only animals, plants, and bacteria are composed of cells.

All organisms are composed of cells.

Answers

All organisms are composed of cells.

Match each lab incident to the item of PPE that will protect you from it. Each item of PPE will only be used once.
While picking up a buret, an unknown solution left by a previous solution drips onto your hand._______________
While pulling an empty beaker off the shelf at the beginning of lab, it slips out of your hand onto the floor _______
While checking on a stirring solution, the solution splashes up towards your face. _______
While transferring a solution from a flask to a beaker, the solution accidentally spills down the front of the lab bench, __________
A. Gloves
B. Lab coat
C. Goggles
D. Closed-toe shoes

Answers

While picking up a buret, an unknown solution left by a previous solution drips onto your hand - Gloves

While pulling an empty beaker off the shelf at the beginning of lab, it slips out of your hand onto the floor - Closed-toe shoes

While checking on a stirring solution, the solution splashes up towards your face - Goggles

While transferring a solution from a flask to a beaker, the solution accidentally spills down the front of the lab bench - Lab coat

Explanation:

The full form of PPE is 'Personal Protective Equipment'.The PPE items we use in labs are : Lab coat: Protection of clothing and skin from accidental spilling of hot liquid or toxic substances. Gloves: Protection from hands from  chemicals, hot objects, sharp tools, or electricityGoggles: Protection of the eye from any chemicals, toxic vapor, chemical debrisFace shield:  Protection of the face from any chemicals, toxic vapor, chemical debrisClosed-toe shoes: Protection from feet from  chemicals, hot objects, sharp tools, or electricity

So, according to the question. the matches will be:

While picking up a buret, an unknown solution left by a previous solution drips onto your hand - Gloves

While pulling an empty beaker off the shelf at the beginning of lab, it slips out of your hand onto the floor - Closed-toe shoes

While checking on a stirring solution, the solution splashes up towards your face - Goggles

While transferring a solution from a flask to a beaker, the solution accidentally spills down the front of the lab bench - Lab coat

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How many molecules are there in 5.9 moles of NaCl?

Answers

The number of molecules= 3.55 x 10²⁴

Further explanation

Given

5.9 moles of NaCl

Required

The number of molecules

Solution

The mole is the number of particles(molecules, atoms, ions) contained in a substance  

1 mol = 6.02.10²³ particles

Can be formulated

N=n x No

N = number of particles

n = mol

No = Avogadro's = 6.02.10²³

So for 5.9 moles :

= 5.9 x 6.02 x 10²³

= 3.55 x 10²⁴

how many equivalent statements are needed to convert 23.4 Gm into mm? 20 points!

Answers

Answer:

23.4 x 10¹²mm

Explanation:

 Given problem;

  Convert Gm to mm;

   Gm  = Gigameters

    mm  = millimeters

   1 Gigameter  = 1 x 10⁹m

    1000mm = 1 m

To convert from Gm to mm;

       23.4 Gm x \(\frac{1 x 10^{9} m}{1Gm}\) x \(\frac{1000mm}{1m}\)   = 23.4 x 1 x 10⁹ x 10³   =

                                                    = 23.4 x 10¹²mm

Place the following metals in order of most reactive to least:
Aluminium
Calcium
Copper
Iron
Magnesium
Sodium
Zinc

Answers

Answer:

Sodium

Calcium

Magnesium

Aluminium

Zinc

Iron

Copper

Explanation:

Arrange the following bonds in order of INCREASING bond strength. (Note: SMALLEST BOND STRENGTH FIRST. LARGEST BOND STRENGTH LAST) A. C-I

Answers

Since the fluorine atom has a higher electronegativity than carbon (4.0 vs. 2.5), the carbon-fluorine bond has a significant polarity/dipole moment.

What does bonds mean in chemistry?

Chemical bonds maintain the interconnectedness of molecules' atoms. Electrostatic forces between negatively charged electrons and positively charged atomic nuclei produce bonds (the positions of which in space are determined by quantum mechanics). Molecules and crystals are created by the formation of chemical bonds, which are long-lasting attractions between atoms or ions. Covalent bonds and ionic bonds both involve the sharing of electrons, while ionic bonds are formed by electrostatic attraction between two ions that have opposing charges.

Why form chemical bonds?

The most straightforward explanation is that atoms are trying to get into the most stable (lowest-energy) state they can. Many atoms become stable when they satisfy the octet rule or have their valence shell completely filled with electrons (by having eight valence electrons). Atoms swap or trade their valence electrons in order to create bonds. It is possible for the valence electrons, which make up an atom's outermost energy level, to interact chemically. All chemical bonds are built on valence electrons.

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The complete question is:

Arrange the following bonds in order of INCREASING bond strength. (Note: SMALLEST BOND STRENGTH FIRST. LARGEST BOND STRENGTH LAST)

A. C-I

B. C-F

C. C-Br

D. C-I

E. Bond strengths are equal.

........URGENT PLEASE HELP............

........URGENT PLEASE HELP............

Answers

Answer:

12.0778

Explanation:

For each pair of
concentrations, tell which
represents the more acidic solution.
a. [H*] = 1.2 x 10-³ M or
[H*]= 4.5 x 10-4 M
b. [H*] = 2.6 x 10-6 M or
[H*] = 4.3 x 10-8 M
c. [H*] = 0.000010 M or
[H*] = 0.0000010 M

Answers

Acids and bases can be measured using a pH scale. The scale has a range of 0 to 14. An indicator called Litmus paper is used to determine if a chemical is an acid or a basic. Here among the given pair, the solution which is more acidic is option A.

The H⁺ ion concentration's negative logarithm is known as pH. As a result, the meaning of pH is justified as the strength of hydrogen. Strongly acidic solutions are those with a pH value of 0, which is known. Additionally, as the pH value rises from 0 to 7, the acidity decreases, while solutions with a pH of 14 are classified as very basic solutions.

pH = -log [H⁺]

a. pH = -log [ 1.2 x 10⁻³] = 2.92

-log [4.5 x 10⁻⁴] = 3.34

b. -log [2.6 x 10⁻⁶] = 5.58 , -log [ 4.3 x 10⁻⁸] = 7.36

c.  -log [ 0.000010] = 5 ,  -log [ 0.0000010] = 6

Thus the correct option is A.

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Choose an example of a reaction to which Markovnikov's rule applies.

O CH₂=CH-CH2-CH3 + HBr CH₂ Br=CH2-CH2-CH3

O CH,=CH-CH, CH3 + HBr → CHg =CHBr–CH2–CH3

O CH,=CH-CH,—CH, + HBr → CH,Br–CHBr–CH2–CH, + HBr CH₂Br-CH2-CH2-CH3

O CH₂=CH-CH2-CH3 O CH,=CH-CH2–CH3 + HBr → CH3–CHBr–CH2–CH3

Answers

The example of a reaction to which Markovnikov's rule applies is: CH₂=CH-CH₂-CH₃ + HBr → CH₂Br-CH₂-CH₂-CH₃

In this reaction, the hydrogen atom from HBr adds to the carbon atom with the fewer alkyl substituents (less substituted carbon), while the bromine atom adds to the carbon atom with more alkyl substituents (more substituted carbon). This follows Markovnikov's rule, which states that in the addition of a protic acid (such as HBr) to an asymmetrically substituted alkene, the hydrogen atom adds to the less substituted carbon and the other atom adds to the more substituted carbon.

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What is the molar mass of H2CO3

Answers

Answer:

Molar mass of H2CO3 : 62.03 g/mol

62.03 g/mol is the molar mas of H2CO3

What solute particles are present in an aqueous solution of ch3coch3 c h 3 c o c h 3 ?.

Answers

Only one solute particles are present in an aqueous solution of CH₃COCH₃.

What is electrolytes?

When dissolved in water, electrolytes are materials that have a natural electrical charge that is either positive or negative. In addition to other things, they support your body's ability to control chemical processes and keep the fluid levels inside and outside of your cells in equilibrium.

Electrolytes include substances like sodium, potassium, calcium, magnesium, chloride, and phosphate.

The electrolyte category also includes water, which puts it in the same group as necessary minerals.

Therefore, Only one solute particles are present in an aqueous solution of CH₃COCH₃.

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18) Identify a characteristic of halogens.A) forms water in reactionsB) absorbs water in reactionsC) powerful reducing agentsD) powerful oxidizing agentsE) inert

Answers

Among the following, the characteristic of halogen is D) Powerful oxidizing agents

Why are halogens powerful oxidizing agents?


A characteristic of halogens is that they are powerful oxidizing agents. This means that they have a strong ability to gain electrons from other substances, making them highly reactive.

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Calculate the molar concentration of a solution containing 3. 0 moles of NaCl in 325 milliliters of water.

Answers

The molar concentration of the solution containing 3.0 moles of NaCl in 325 milliliters of water is approximately 9.23 M.

To calculate the molar concentration of a solution, we use the formula:

Molar Concentration (M) = Moles of solute / Volume of solution (in liters)

In this case, we have 3.0 moles of NaCl and 325 milliliters of water. First, we need to convert the volume of the solution to liters by dividing it by 1000:

Volume of solution = 325 mL / 1000 = 0.325 L

Now we can substitute the values into the formula to calculate the molar concentration:

M = 3.0 moles / 0.325 L

M = 9.23 M

Therefore, the molar concentration of the solution containing 3.0 moles of NaCl in 325 milliliters of water is approximately 9.23 M.

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which of the statements regarding beta particles are true? beta particles have a mass number of 0. beta-particle formation is accompanied by the conversion of a proton into a neutron. beta particles have an atomic number of 1. beta-particle formation is accompanied by the conversion of a neutron into a proton.

Answers

The statement that is true regarding beta particles is D. "Beta-particle formation is accompanied by the conversion of a neutron into a proton."

Beta particles are high-energy electrons or positrons that are emitted during certain types of radioactive decay processes. Beta decay occurs when an unstable nucleus undergoes a transformation in order to reach a more stable state. In beta-minus decay, a neutron in the nucleus is converted into a proton, releasing a beta particle (high-energy electron) and an antineutrino. The conversion of a neutron into a proton increases the atomic number of the nucleus by one.

The statement that beta particles have a mass number of 0 is incorrect. Beta particles do have mass, although they are much less massive compared to protons or neutrons. Similarly, the statement that beta particles have an atomic number of 1 is incorrect. The atomic number refers to the number of protons in an atom, and beta particles are not atoms themselves. Beta particles are high-energy particles emitted from the nucleus during beta decay.

Therefore, the only true statement regarding beta particles is that their formation is accompanied by the conversion of a neutron into a proton, which leads to an increase in the atomic number of the nucleus. Therefore, Option D is correct.

which of the statements regarding beta particles are true?

A. beta particles have a mass number of 0.

B. beta-particle formation is accompanied by the conversion of a proton into a neutron.

C. beta particles have an atomic number of 1.

D. beta-particle formation is accompanied by the conversion of a neutron into a proton.

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How many bonds will an atom of bromine usually form in order to reach an octet of electrons?

Answers

Answer:State the number of valence electrons for a hydrogen atom and a bromine atom in a covalent bond.

Explanation:

show the reaction with hbro2 acting as a bronsted-lowry acid.

Answers

The reaction with HBrO2 acting as a Bronsted-Lowry acid can be represented as follows:

HBrO2 + H2O → BrO2- + H3O+

In this reaction, HBrO2 donates a proton (H+) to water (H2O), which acts as a Bronsted-Lowry base. The proton transfer results in the formation of the bromate ion (BrO2-) and the hydronium ion (H3O+).

It is important to note that HBrO2 is a weak acid, and its ionization in water is not complete. The equilibrium between the acid and its conjugate base is established, and the extent of ionization depends on the acid's dissociation constant (Ka).

The reaction shown above demonstrates the proton transfer from HBrO2 to water, leading to the formation of BrO2- and H3O+

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A length of fishing line measures 5470 cm. How many kilometers is that length? Question options: 5.47 km 0.547 km 54.7 km 0.0547 km

Answers

Answer:

0.0547

Explanation:

5470 cm ÷ 100 = 54,70 m

54,70 m ÷ 1000= 0,0547 km

Answer: B. 0.547 km

Explanation: 1km = 100,000 cm, so

1/100000= x/5470

5470= 100000x

0.547=x

What is Mg ^-2 and SO4^-2=

Answers

MgSo4 will be formed

if an object has a smaller density than water what will it do when it is released underwater?

Answers

If an object has a smaller density than water, it will float when released underwater.

Density is a measure of how tightly packed the matter in an object is. If an object is less dense than water, it means that it has fewer particles in a given space compared to water. This causes it to displace a smaller amount of water, resulting in it being buoyant. When the object is released underwater, it will rise to the surface because the upward force exerted by the water on the object is greater than the force of gravity pulling the object down. This phenomenon is known as buoyancy, and it is the reason why objects with a smaller density than water, such as wood and plastic, float in water. Answering in more than 100 words, it is important to note that buoyancy is affected not only by density but also by the shape and size of the object and the properties of the liquid in which it is submerged.

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A pharmaceutical company is making a large volume of nitrous oxide (NO). They predict they will be able to make a maximum amount of 4860 grams with the materials they have in stock. From the previous 10 volumes they have made, they know that the percent yield of this reaction is fairly low at 47%. How much will the actual yield be? A. 228 grams B. 2284 grams C. 10340 grams D. 486 grams

Answers

Answer:

The answer is "Option B"

Explanation:

From the query, the following knowledge is derived:  

Yield in percentage = 47%  

Performance of theory = 4860 g  

Actual yield Rate =?  

The percentage return is defined simply by the ratio between both the real return as well as the conceptual return multiplied by the 100. It's also represented as numerically:

\(Rate = \frac{Existing \ Rate} {Theoretical \ Rate} \times 100\)

Now We can obtain the percent yield as followed using the above formula:  

\(\text{Yield in percentage}= \frac{Actual \ yield \ Rate} {Theorical \ Rate} \times 100\)

\(47\% = \frac{Actual \ yield \ Rate}{4860}\)

The value of the Actual yield Rate =\(47\% \times 4860\)

                                                        \(= \frac{47}{100} \times 4860 \\\\ = 2284.2 g\)

The Actual yield Rate= 2284.2 g.

Which Ionic Chemical Formula below is INCORRECT? NaCl MgO Ba2Cl Li2S

Answers

Answer:

Li2S

Explanation:

Provide any critical observations/changes to the reaction mixture upon addition of the acid. Propose what this might suggest about possible functional groups present on your unknown starting material and briefly defend your proposal. A white precipitate forms with each drop of sulfuric acid.

Answers

This suggests that the unknown starting material is likely an organic compound containing a carboxylic acid functional group.

What is compound ?

Compound is a combination of two or more elements which are chemically bonded together. Compounds can exist in both organic and inorganic forms, and are formed when atoms of different elements combine to form molecules. Inorganic compounds are generally composed of metal and non-metal elements, while organic compounds are composed of only carbon and hydrogen atoms. Compounds can also be classified according to their physical state, such as solid, liquid, or gas. Compounds are important in many areas of science, such as chemistry, physics, and biology, and play an essential role in the production of many products, including medicines, plastics, and fuels.

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what happens when potassium reacts with fluorine to produce potassium fluoride

Answers

Answer:

In order to obtain eight valence electrons (an octet), the potassium atom will transfer its single valence electron to the fluorine atom.

Calculate the number of moles in 44.8L of CO2 at STP.

Answers

Answer:

the answer is 2 moles

Explanation:

in 22.4 l there is 1 mole (avogardo law) so by applying unitary method we can see that in 44.8 l there will be 2 moles of gas.

When producing XY as shown in the equation, the energy of the reactants is 732 kJ/mol and the total bond energy of the product side is 1256 kJ/mol.
2X + Y2 --> 2XY
What is the total energy of the reaction?

show your work with picture provided

When producing XY as shown in the equation, the energy of the reactants is 732 kJ/mol and the total bond

Answers

The reaction has an 836 kJ/mol total energy.

What does H stand for?

The reaction is endothermic if the change in enthalpy is positive. A lower enthalpy indicates a process using less energy. Enthalpy (H) is a measure of the overall heat content of the system.

The difference between the energies of the reactants and products can be used to compute the reaction's overall energy.

energy required to break the bonds in Y2 = (732 kJ/mol) × 2 = 1464 kJ/mol

Determine the energy produced during the products' bond formation.

energy released by forming the bonds in XY = (1256 kJ/mol) / 2 = 628 kJ/mol

Determine the reaction's overall energy.

Total reaction energy equals energy released by creating the bonds in XY minus energy expended to break the bonds in Y2.

total energy of the reaction = 1464 kJ/mol - 628 kJ/mol

total energy of the reaction = 836 kJ/mol

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The protein--iron compound that has the bonding capabilities for the transport of oxygen and carbon dioxide is:

Answers

It is hemoglobin.

What is hemoglobin and its composition?

In the red blood cells (erythrocytes) of vertebrates, hemoglobin, an iron-containing protein, transports oxygen from the lungs to the body's tissues and organs and returns carbon dioxide to the lungs. In a complete blood cell (CBC) test, the amount of hemoglobin in the blood is often measured.

A globin group is surrounded by four heme groups, which together form a tetrahedral shape in each hemoglobin molecule. Heme is an organic complex known as a porphyrin that has an iron atom linked to it. Heme makes up only 4% of the weight of the molecule. As the blood circulates between the lungs and the tissues, the iron atom is what holds oxygen in place. Each hemoglobin molecule contains four iron atoms, and as a result, it has the capacity to bind four oxygen molecules. Two linked pairs of polypeptide chains make up globin.

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