The reduction half-reaction for the given overall galvanic cell reaction can be determined by breaking down the reaction into half-reactions for oxidation and reduction.
First, let's identify the oxidation half-reaction. In the overall reaction, we can see that carbon dioxide (CO2) is being reduced to carbon monoxide (CO), while silver (Ag) ions are being oxidized to silver metal (Ag). Therefore, the oxidation half-reaction can be written as:
2 Ag (s) → 2 Ag+ (aq) + 2 e-
Next, let's identify the reduction half-reaction. We can see that silver ions (Ag+) are being reduced to silver metal (Ag), while carbon dioxide (CO2) is being oxidized to carbon monoxide (CO). Therefore, the reduction half-reaction can be written as:
CO2 (aq) + 2 e- → CO (s)
Note that the reduction half-reaction is written in the reverse direction compared to the overall reaction because it represents the reduction of CO2, while the overall reaction shows the reduction of Ag+.
To balance the number of electrons transferred in both half-reactions, we can multiply the oxidation half-reaction by 2:
4 Ag (s) → 4 Ag+ (aq) + 4 e-
Now, the number of electrons transferred is balanced in both half-reactions.
In summary, the reduction half-reaction for the given overall galvanic cell reaction is:
CO2 (aq) + 2 e- → CO (s)
This half-reaction represents the reduction of carbon dioxide to carbon monoxide in the galvanic cell.
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proof partition Function for Semi classical system has N particles Z - Zr NI
The partition function Z for a semi-classical system with N particles can be expressed as the product of the translational partition function Zr and the internal partition function NI due to the statistical independence of the translational and internal degrees of freedom in the system.
To prove this, we start by considering the partition function for a system with N particles:
Z = ∑ exp(-βE)
where β = 1/(k*T) is the inverse temperature, E is the energy of a particular state, and the sum is taken over all possible states of the system.
To separate the translational and internal degrees of freedom, we can write the total energy as the sum of the kinetic energy of translation (ET) and the internal energy (EI). Therefore, E = ET + EI.
Now, we rewrite the partition function as:
Z = ∑ exp(-β(ET + EI))
Expanding this expression, we can split the summation into two parts:
Z = ∑ exp(-βET) * exp(-βEI)
The first term, exp(-βET), represents the translational partition function Zr, which depends on the volume (V) and the thermal de Broglie wavelength (λ) of a single particle. It can be written as Zr = (V / λ^3)^N.
The second term, exp(-βEI), represents the internal partition function NI, which accounts for the internal degrees of freedom of the particles.
Combining these results, we obtain:
Z = Zr * NI
Thus, we have proved that for a semi-classical system with N particles, the partition function Z can be expressed as the product of the translational partition function Zr and the internal partition function NI, i.e., Z = Zr * NI.
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Note- The complete question is "Prove that for a semi-classical system with N particles, the partition function Z can be expressed as the product of the translational partition function Zr and the internal partition function NI, i.e., Z = Zr * NI."
THREE QUESTIONS ANSWER TWO Question 1 a) Determine the pulse duration of a periodic pulse train whose duty cycle is \( 15 \% \) and period is 115 nanoseconds.
The pulse duration of periodic pulse train with a duty cycle of 15% and a period of 115 nanoseconds is 17.25 nanoseconds.
Duty cycle = 15% or 0.15
Time period = 115 nanoseconds
The ratio of the amount of time the signal spends in the "on" state to its overall duration is known as the duty cycle. The signal is on for 15% of the entire period when the duty cycle is given as 15% in this instance. Duty cycles are a term used to represent the percentage of time that an electrical signal is active in a device, such as the power switch in a switching power supply, or when an organism, like a neuron, fires an action potential.
Calculating the duty cycle and the period of the pulse train -
Pulse duration = Duty cycle x Period
= 0.15 x 115
= 17.25
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a railroad car with a mass of 90,000 kg is traveling along a straight, horizontal track at a constant speed of 2 m/s. the car collides with a second railroad car, also with a of 90,000 kg that is initially at rest. The railroad cars stick together after the collision, as shown in the figure.
1) 0.5 m/s
2) 1 m/s
3) 2 m/s
Answer:
I think it's 2.
Explanation:
The weight should transfer half of it's velocity to the other one. or its 1
NEED HELP
What is the temperature in kelvin of a gas if it is allowed to expand from 1.50 L to 4.50 L? The initial temperature is 10.0°C and pressure is constant throughout the change. Which equation should you use?
Answer:
Explanation:
V1/T1 =V2/T2 at constnant pressure
Answer:
c
Explanation:
CAN SOMEONE HELP ASAP!!
Answer:
1.melting
2.freezing
3.
Explanation:
That's all I got sorry
Answer:
Look at the picture
Explanation:
please can someone help me define atomic number, Mass number and isotopy urgently
Which do you think will cool the fastest?
sand
water
air
metal
show transcribed data consider two organic molecules, ethanol and benzene. one dissolves in water and the other does not. why? they have different molar masses. one is ionic, the other is not one is an electrolyte, the other is not. ethanol contains a polar o-h bond, and benzene does not.
Benzene lacks a polar O-H bond, but ethanol does. Benzene C6H6 with ethanol C2H6O.
Benzene fails the iodoform test, whereas ethanol does.
While ethanol burns with a non-luminous flame, benzene produces a sooty flame.
Iodoform testing shows that ethanol passes whereas benzene does not.
In contrast to benzene, which generates a sooty flame, ethanol burns with a non-luminous flame.
Water does not mix with benzene, but organic solvents do.
It is a colorless liquid with a pleasant scent.
Benzene has a high melting point and a moderate boiling point.
It burns with a sooty flame and is quite flammable.
A clear, colorless liquid, ethanol has a distinct flavor of burning with a nice aroma. It has high flammability. Ethanol combines easily with water and a variety of organic liquids and is used to dissolve other chemical compounds.
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Q-3 Determine the fugacity in atm for pure ethane at 310 K and 20.4 atm and change in the chemical potential between this state and a second state od ethane where temperature is constant but pressure is 24 atm.
The fugacity in atm for pure ethane at 310 K and 20.4 atm is given by the equation: f = 20.4 exp (-Δg1/RT). The change in chemical potential between this state and a second state of ethane where the temperature is constant but the pressure is 24 atm is -0.0911RT.
Fugacity is a measure of the escaping tendency of a component in a mixture, which is defined as the pressure that the component would have if it obeyed ideal gas laws. It is used as a correction factor in the calculation of equilibrium constants and thermodynamic properties such as chemical potential. Here we need to determine the fugacity in atm for pure ethane at 310 K and 20.4 atm and the change in the chemical potential between this state and a second state of ethane where the temperature is constant but the pressure is 24 atm. So, using the formula of fugacity: f = P.exp(Δu/RT) Where P is the pressure of the system, R is the gas constant, T is the temperature of the system, Δu is the change in chemical potential of the system. Δu = RT ln (f / P)The chemical potential at the initial state can be calculated using the ideal gas equation as: PV = nRT
=> P
= nRT/V
=> 20.4 atm
= nRT/V
=> n/V
= 20.4/RT The chemical potential of the system at the initial state is:
Δu1 = RT ln (f/P)
= RT ln (f/20.4) Also, we know that for a pure substance,
Δu = Δg. So,
Δg1 = Δu1 The change in pressure is 24 atm – 20.4 atm
= 3.6 atm At the second state, the pressure is 24 atm.
Using the ideal gas equation, n/V = 24/RT The chemical potential of the system at the second state is: Δu2 = RT ln (f/24) = RT ln (f/24) The change in chemical potential is Δu2 – Δu1 The change in chemical potential is
Δu2 – Δu1 = RT ln (f/24) – RT ln (f/20.4)
= RT ln [(f/24)/(f/20.4)]
= RT ln (20.4/24)
= - 0.0911 RT Therefore, the fugacity in atm for pure ethane at 310 K and 20.4 atm is:
f = P.exp(Δu/RT)
=> f
= 20.4 exp (-Δu1/RT)
=> f
= 20.4 exp (-Δg1/RT) And, the change in the chemical potential between this state and a second state of ethane where the temperature is constant but pressure is 24 atm is -0.0911RT. Therefore, the fugacity in atm for pure ethane at 310 K and 20.4 atm is given by the equation: f = 20.4 exp (-Δg1/RT). The change in chemical potential between this state and a second state of ethane where the temperature is constant but the pressure is 24 atm is -0.0911RT.
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draw the organic product formed when 1−hexyne is treated with h2o, h2so4, and hgso4. click the draw structure button to launch the drawing utility.
The organic product formed when 1−hexyne is treated with the H₂O, H₂SO₄ and HgSO₄ is 2 - hexanone.
The reaction of the 1−hexyne is treated with the H₂O, H₂SO₄ and HgSO₄ is given as :
CH₃- CH₂ - CH₂ - CH₂ - C ≡ CH + H₂O / H₂SO₄ / HgSO₄ ----->
1 - hexyne CH₃- CH₂ - CH₂ - CH₂ - CO - CH₃
2 - hexanone
Thus, the when the 1 - hexyne react with the H₂O, H₂SO₄ and HgSO₄ is 2 - hexanone the product is formed is known as the 2 - hexanone. the above is the reaction for the formation of 2 - hexanone.
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T or F: All electrons are alike
Answer:
True
Explanation:
Every electron in the universe has exactly the same mass, and exactly the same charge.
predict product of AlBr3 + Mg2N3
Answer:
2AlBr3 + Mg2N3 -------> 2AlN + 3MgBr2
Aluminum Nitride and Magnesium Bromide are the products of this reaction
Series circuits are used in ___________ and some holiday lights.
Series circuits are mainly used in home appliances. They are also used batteries of some electrical devices other than in holiday lights.
What is series circuits?In a series circuits, the electrical components are connected in a series thus in a back to back connection. For example the light bulbs where the second leg of the first bulb is is connected to the first leg of the second bulb and so on.
Resistors are used here to control the current flow and they are also connected in a series fashion. The sum of voltage drops for all the components will be equal to the source voltage. Here we can apply the Ohm's law.
Ohm's law states that the voltage is the product of current and resistance. Series circuit is also used in batteries and in other households such as in refrigerators.
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hich statement about the quantum mechanical solution for the hydrogen atom is incorrect? group of answer choices
A positive value must exist for the ml quantum number. This assertion regarding the hydrogen atom's quantum mechanical solution is false.
Can 0 be equal to the MS quantum number?An orbital is described by the three integer quantum numbers (n, l, and m) 0, 1, 2, and 3. Zero is not an option for the main quantum number (n).
A ground state orbital of type 1s with magnetic quantum number ml = 0 houses the lone electron in hydrogen.
The same electron can also be stimulated to higher energy levels like 2p, 3p, or 3d.
Higher np sub-levels of the hydrogen atom have magnetic quantum numbers, which are magnetic quantum numbers -1, 0 and 1.
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A screw decreases the amount of work done.
True
False
Answer:
tru
Explanation:
Practice Run Just need a bit of help! Good amount of points!
According to LeChatelier's principle, what are 3 general ways that you can reverse a reaction when it is at equilibrium. Select all that apply.
Adding concentration of product
Adding concentration of product
Adding concentration of reactant
Adding concentration of reactant
Keeping the concentration the same
Keeping the concentration the same
Changing temperature
Changing temperature
Changing the state of matter
Changing the state of matter
Changing the color
Changing the color
Changing Pressure
The 3 general ways by which a system in equilibrium can be reversed are by changing the concentration of the reactants of products, changing the pressure of the system, and changing the temperature of the system.
Le Chatelier's principleLe Chatelier's principle state that when a reaction is in equilibrium and one of the constraints that affect the rate of reactions is applied to the system, the equilibrium shifts so as to cancel out the effects of the constraints.
The constraints being referred to by Le Chatelier are concentration, pressure, and temperature. Increasing or decreasing the pressure of a system in equilibrium will shift the equilibrium to the sides with the lower moles or higher moles respectively.
Increasing the concentration of the reactants will shift the equilibrium toward the product side while increasing the concentration of the products will shift the equilibrium toward the reactant side.
In the same vein, increasing the temperature of a system will sift the equilibrium towards the product if the system itself is endothermic. If the system is exothermic, a reversal will occur.
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What charge would each element obtain when it becomes an ion? a) aluminum e) lodine
b) lithium c) barium f) phosphorus g) sulfur d) bromine h) magnesium
Aluminum forms an ion of +3 while the bromine atom form an ion of -1.
What is an ion?An ion is an atom which has lost/gained one or more electrons. The ion will be positive if an electron is lost and will be negative when an electron is gained by the specie.
The ions formed by each of the species is;
Al = +3I = -1Li = +1Ba= +2P = -3S = -2Br = -1Mg = +2Learn more about ions:https://brainly.com/question/1782326
a sample of calcium bromide contains 20% calcium and 80% bromine by mass. what is the empirical formula of the compound formed?
A sample of calcium bromide contains 20% calcium and 80% bromine by mass. The empirical formula of the compound formed is CaBr2
Given:
A substance with the chemical formula 20% Ca and 80% Br.
In search of:
When the compound's molecular weight is 200.
Let's say that the mixture formed is 100.
Let's search for the mole of Ca and Br individually now.
Ca mole = 20/40 = half
"Mole of Br" = "80/80"
CaBr2 is the result of the 1:2 ratio between Ca and Br.
So, the empirical formula is CaBr2.
An empirical formula is a chemical formula for a compound that only specifies the ratios of the elements present in the molecule and not the exact number or arrangement of atoms. This would be the element to whole number ratio of the lowest valued compound.
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2. Randy has a 500 g of water at 20°C. If he wants the final temperature of the water to be 75°C (the change in temperature will be 55°C), how many Joules of heat will he need to add? (Cwater = 4.184 J/(g°C)
Answer:
115060 J
Explanation:
From the question given above, the following data were obtained:
Mass (M) = 500 g
Initial temperature (T1) = 20 °C
Final temperature (T2) = 75 °C
Change in temperature (ΔT) = 55 °C
Specific heat capacity (C) = 4.184 J/g°C
Heat (Q) required =?
The heat required to change the temperature of the water can obtained as follow:
Q = MCΔT
Q = 500 × 4.184 × 55
Q = 115060 J
Therefore, the heat needed to change the temperature of the water is 115060 J.
Concentrated sulfuric acid ( 18.3m ) has a density of 1.84g/ml. (a) How many moles of are in each milliliter …
Concentrated sulfuric acid ( 18.3m ) has a density of 1.84g/ml.
(a) How many moles of H2SO4 are in each milliliter of solution?
(b) What is the mass % of H2SO4 in the solution?
A) 0.0187 moles of H2SO4 are in each milliliter of solution.
B) 99.95% of H2SO4 in the solution.
(a) The molarity of a solution is defined as the number of moles of solute per liter of solution. To calculate the number of moles of H2SO4 in each milliliter of the 18.3 M solution, we first need to calculate the number of moles in one liter: 18.3 M = 18.3 mol/L
So one liter of the solution contains 18.3 moles of H2SO4. Since the density of the solution is 1.84 g/mL, the mass of one liter of solution is: 1 L x 1.84 g/mL = 1840 g
We can use the molar mass of H2SO4 to convert the mass of H2SO4 in one liter of solution to moles: 1 L x (1840 g/1000 mL) x (1 mol/98.07 g) = 18.74 mol
(b) The mass percentage of a solute in a solution is defined as the mass of the solute divided by the mass of the solution, multiplied by 100%. To calculate the mass percentage of H2SO4 in the solution, we first need to calculate the mass of H2SO4 in one milliliter of the solution: 0.0187 mol/mL x 98.07 g/mol = 1.83 g/mL
So one milliliter of the solution contains 1.83 grams of H2SO4. The mass of one milliliter of the solution is: 1 mL x 1.84 g/mL = 1.84 g
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Aqueous sodium hydroxide reacts with carbon dioxide gas to yield soluble sodium carbonate and liquid
water. What is the chemical equation?
Explanation:
i have done
see the picture
and please mark me brainiest
mass of 2 into 10 to power 21 number of atoms of an element is 0.4 gram what is the mass of 0.5 mole of the elements
The mass of 0.5 mole of the element is approximately 6.025 grams.
To calculate the mass of 0.5 mole of the element, we need to know the molar mass of the element.
Given that the mass of 2 x 10^21 atoms of the element is 0.4 grams, we can use this information to find the molar mass.
The number of atoms in 1 mole of any substance is given by Avogadro's number, which is approximately 6.022 x 10^23 atoms/mol.
First, we calculate the molar mass of the element using the given information:
Molar mass = Mass of 2 x 10^21 atoms / Number of moles of 2 x 10^21 atoms
Molar mass = 0.4 g / (2 x 10^21 atoms / (6.022 x 10^23 atoms/mol))
Molar mass ≈ 0.4 g / (3.32 x 10^-2 mol)
Molar mass ≈ 12.05 g/mol
Now that we know the molar mass of the element is approximately 12.05 g/mol, we can calculate the mass of 0.5 mole of the element:
Mass = Molar mass x Number of moles
Mass = 12.05 g/mol x 0.5 mol
Mass = 6.025 grams
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Estimate the value of the equilibrium constant at 610 K for each of the following reactions.2NO2(g)⇋N2O4(g)ΔH∘fforN2O4(g)=9.16kJ/molBr2(g)+Cl2(g)⇋2BrCl(g)ΔH∘fforBrCl(g)=14.6kJ/molΔG∘fforBrCl(g)=−1.0kJ/mol
The estimated equilibrium constant for the reaction Br2(g) + Cl2(g) ⇋ 2BrCl(g) at 610 K is 1.16.
To estimate the equilibrium constant, we can use the equation:
ΔG° = -RTln(K)
where ΔG° is the standard Gibbs free energy change, R is the gas constant, T is the temperature in Kelvin, and K is the equilibrium constant.
For the reaction 2NO2(g) ⇋ N2O4(g), the given ΔH°f for N2O4(g) is 9.16 kJ/mol. Using this value, we can calculate the standard Gibbs free energy change:
ΔG° = ΔH° - TΔS°
where ΔS° is the standard entropy change. We do not have this value, but we can assume it is roughly constant for this type of reaction. Thus, we can estimate ΔG° to be:
ΔG° ≈ ΔH° = 9.16 kJ/mol
At 610 K, we have:
ΔG° = -RTln(K)
-9100 J/mol = -(8.314 J/mol/K)(610 K)ln(K)
ln(K) ≈ 2.37
K ≈ e^2.37 = 10.7
Therefore, the estimated equilibrium constant for the reaction 2NO2(g) ⇋ N2O4(g) at 610 K is 10.7.
For the reaction Br2(g) + Cl2(g) ⇋ 2BrCl(g), we are given the ΔH°f for BrCl(g) as 14.6 kJ/mol and the ΔG°f for BrCl(g) as -1.0 kJ/mol. Using the same assumptions as before, we can estimate ΔG° to be:
ΔG° ≈ ΔH° = 14.6 kJ/mol
At 610 K, we have:
ΔG° = -RTln(K)
-1000 J/mol = -(8.314 J/mol/K)(610 K)ln(K)
ln(K) ≈ 0.15
K ≈ e^0.15 = 1.16
Therefore, the estimated equilibrium constant for the reaction Br2(g) + Cl2(g) ⇋ 2BrCl(g) at 610 K is 1.16.
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An atom of sodium-23 (Na-23) has a net charge of
+1. Identify the number of protons, neutrons, and
electrons in the atom. Then, explain how you
determined the number of each type of particle.
Use the
periodic table to help you.
Answer:
Protons= 11
neutrons= 12
electrons = 10
Explanantion:
Look for Na on periodic table
Atomic Number = 11
Atomic Mass = 23 (round it to be an integer)
Number of protons = Atomic number = 11
Number of neutrons = Atomic mass - atomic number = 23-11 =12
Number of electrons = 11 - e = ´+1 , electrons = 10
Answer:
Protons= 11
neutrons= 12
electrons = 10
Explanation:
That should be the answer :)
How many valence electrons does magnesium(Mg) have?
Magnesium have two valence electrons. Because the outer energy level for the magnesium atom is 3 and it has two electron in this energy level.
The Valence electrons are defined as the electrons that located in the outermost electron shell of an atom. These valence electrons being the furthest from the nucleus and thus the least tightly held by the atom are the electrons that participate in bonds and reactions. The number of valence electrons that an element has determines its reactivity, electronegativity and the number of bonds it can form. We can use the periodic table to help to determine how many valence electrons an element specifically a neutral atom of the element has. Looking at the group that the element is in as the group number indicates the number of valence electrons that the element has.
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Calculate the volume of 5.0% w/v of bleach (NaOCl) you would
need for oxidation of 10 g of cyclohexanol. Show calculations.
To oxidize 10 g of cyclohexanol, 200 mL of 5.0% w/v bleach (NaOCl) is needed.
What is the required volume of 5.0% w/v bleach (NaOCl) needed to oxidize 10 g of cyclohexanol?Before calculating the volume of bleach, we need to find:
\(Mass of cyclohexanol = 10 g\\Concentration of bleach (NaOCl) = 5.0\% w/v\\Convert the mass of cyclohexanol to moles.\\Molar mass of cyclohexanol (C6H12O) = 100.16 g/mol\\Moles of cyclohexanol = mass / molar mass\\Moles of cyclohexanol = 10 g / 100.16 g/mol\)
Determine the stoichiometry between cyclohexanol and bleach.
From the balanced equation for the oxidation of cyclohexanol, we know that:
1 mole of cyclohexanol reacts with 1 mole of bleach (NaOCl)
Calculate the moles of bleach required.
\(Moles\ of\ bleach\ (NaOCl) = moles\ of\ cyclohexanol\)
Calculate the volume of bleach using its concentration.
\(Volume\ (in\ mL) of\ bleach = (moles\ of\ bleach / concentration\ of\ bleach) * 1000\\Volume (in mL) of bleach = (moles of bleach / 0.05) * 1000\\Substituting the value of moles of bleach\\Volume (in mL) of bleach = (moles of cyclohexanol / 0.05) * 1000\\Substituting the value of moles of cyclohexanol\\Volume (in mL) of bleach = (10 g / 100.16 g/mol) / 0.05 * 1000\)
Simplifying:
\(Volume\ (in\ mL)\ of\ bleach = 199.64\ mL\)
Therefore, to oxidize 10 g of cyclohexanol, you would need approximately 200 mL of 5.0% w/v bleach (NaOCl).
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Please help me with this
choose the compound that should have the highest melting point according to the ionic bonding model. group of answer choices cao srcl2 ki cas
The compound with the highest melting point according to the ionic bonding model would be CaO (calcium oxide).
Ionic bonding occurs between atoms with a large difference in electronegativity, resulting in the transfer of electrons from the metal to the non-metal. In CaO, calcium (a metal) loses two electrons to oxygen (a non-metal), resulting in the formation of Ca2+ and O2- ions. These ions are held together by strong electrostatic forces, forming an ionic lattice structure.The strength of the electrostatic forces between the ions is directly related to the size of the charges on the ions and the distance between them. Ca2+ has a larger charge than the other cations listed (Sr2+, K+) and O2- has a smaller radius than the other anions listed (Cl-, S2-), meaning the electrostatic forces between Ca2+ and O2- are stronger.This results in a higher melting point for CaO as more energy is required to break the strong electrostatic forces holding the ions together. In addition, CaO has a higher lattice energy (the energy required to separate a mole of a solid ionic compound into its gaseous ions) than the other compounds listed, further contributing to its higher melting point.For more such question on melting point
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plss help . i have no idea
Answer:
Protons and Neutrons have approximately the same mass.
Equal numbers of protons and electrons make an atom neutral.
Protons have a positive charge
Explanation:
Protons and Neutrons have approximately the same mass. - both are 1 amu
Equal numbers of protons and electrons make an atom neutral. - protons are +1 and electrons are -1, so they cancel each other if there are equal amounts.
Protons have a positive charge - this is true.
10 To draw a perfect circle, you'll need: A A protractor B. A sextant С A compass D A spirograph 10 of 10
Answer:
B
Explanation:
Two quick google searches later I grace you with the google has bestowed upon me